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Cerium-Doped Fused-Silica Fibers as Wavelength Shifters

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 Added by Federico De Guio
 Publication date 2019
  fields Physics
and research's language is English




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We have evaluated the performance of a Ce-doped fused-silica fiber as wavelength shifter coupled to a CeF$_{3}$ crystal using electron beams at CERN. The pulse shape and collection efficiency were measured using irradiated (100 kGy) and un-irradiated fibers. In addition, we evaluated the light yield of various Ce-doped fibers and explored the possibility of using them in the future, including for precision timing applications in a high-luminosity collider environment.



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A large number of particle detectors employ liquid argon as their target material owing to its high scintillation yield and its ability to drift ionization charge for large distances. Scintillation light from argon is peaked at 128 nm and a wavelength shifter is required for its efficient detection. In this work we directly compare the light yield achieved in two identical liquid argon chambers, one of which is equipped with PolyEthylene Naphthalate (PEN) and the other with TetraPhenyl Butadiene (TPB) wavelength shifter. Both chambers are lined with enhanced specular reflectors and instrumented with SiPMs with a coverage fraction of approximately 1%, which represents a geometry comparable to the future large scale detectors. We measured the light yield of the PEN chamber to be 39.4$pm$0.4(stat)$pm$1.9(syst)% of the yield of the TPB chamber. Using a Monte Carlo simulation this result is used to extract the wavelength shifting efficiency of PEN relative to TPB equal to 47.2$pm$5.7%. This result paves the way for the use of easily available PEN foils as a wavelength shifter, which can substantially simplify the construction of the future liquid argon detectors.
Ce3+ doped oxide materials are promising for optical emission in the green spectral range. The growth of CaSc2O4:Ce3+ single crystals is reported here for the first time. Laser heated pedestal growth (LHPG) proved to be suitable for this refractive material, if performed in nitrogen of 99.999% purity. If the oxygen content of the growth atmosphere is substantially larger, Ce4+ is formed, which shows no useful optical emission. If the oxygen content is substantially lower, severe evaporation of calcium impedes stable crystal growth. Thermodynamic equilibrium calculations allowed to describe evaporation of species and cerium dopant charging under different growth conditions. The evaporation could be investigated by quadrupole mass spectrometry of emanating gases and by chemical analysis of fibers with ICP-OES. The congruent melting point was confirmed by DTA at 2110 degrees centigrade. Photoluminescence spectrometry of fibers revealed the dependence of optical emission in the green spectral range on growth conditions.
59 - J. Beare , G. Beer , J.H. Brewer 2020
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