In quantum thermodynamics, the standard approach to estimate work fluctuations in unitary processes is based on two projective measurements, one performed at the beginning of the process and one at the end. The first measurement destroys any initial coherence in the energy basis, thus preventing later interference effects. In order to decrease this back-action, a scheme based on collective measurements has been proposed in~[PRL 118, 070601 (2017)]. Here, we report its experimental implementation in an optical system. The experiment consists of a deterministic collective measurement on identically prepared two qubits, encoded in the polarisation and path degree of a single photon. The standard two projective measurement approach is also experimentally realized for comparison. Our results show the potential of collective schemes to decrease the back-action of projective measurements, and capture subtle effects arising from quantum coherence.
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