No Arabic abstract
We investigate the jamming transition in a quasi-2D granular material composed of regular pentagons or disks subjected to quasistatic uniaxial compression. We report six major findings based on experiments with monodisperse photoelastic particles with static friction coefficient $muapprox 1$. (1) For both pentagons and disks, the onset of rigidity occurs when the average coordination number of non-rattlers, $Z_{nr}$ , reaches 3, and the dependence of $Z_{nr}$ on the packing fraction $phi$ changes again when $Z_{nr}$ reaches 4. (2) Though the packing fractions $phi_{c1}$ and $phi_{c2}$ at these transitions differ from run to run, for both shapes the data from all runs with different initial configurations collapses when plotted as a function of the non-rattler fraction. (3) The averaged values of $phi_{c1}$ and $phi_{c2}$ for pentagons are around 1% smaller than those for disks. (4) Both jammed pentagons and disks show Gamma distribution of the Voronoi cell area with same parameters. (5) The jammed pentagons have similar translational order for particle centers but slightly less orientational order for contacting pairs comparing to jammed disks. (6) For jammed pentagons, the angle between edges at a face-to-vertex contact point shows a uniform distribution and the size of a cluster connected by face-to-face contacts shows a power-law distribution.
The jamming scenario of disordered media, formulated about 10 years ago, has in recent years been advanced by analyzing model systems of granular media. This has led to various new concepts that are increasingly being explored in in a variety of systems. This chapter contains an introductory review of these recent developments and provides an outlook on their applicability to different physical systems and on future directions. The first part of the paper is devoted to an overview of the findings for model systems of frictionless spheres, focussing on the excess of low-frequency modes as the jamming point is approached. Particular attention is paid to a discussion of the cross-over frequency and length scales that govern this approach. We then discuss the effects of particle asphericity and static friction, the applicability to bubble models for wet foams in which the friction is dynamic, the dynamical arrest in colloids, and the implications for molecular glasses.
We explore quantitative descriptors that herald when a many-particle system in $d$-dimensional Euclidean space $mathbb{R}^d$ approaches a hyperuniform state as a function of the relevant control parameter. We establish quantitative criteria to ascertain the extent of hyperuniform and nonhyperuniform distance-scaling regimes n terms of the ratio $B/A$, where $A$ is volume coefficient and $B$ is surface-area coefficient associated with the local number variance $sigma^2(R)$ for a spherical window of radius $R$. To complement the known direct-space representation of the coefficient $B$ in terms of the total correlation function $h({bf r})$, we derive its corresponding Fourier representation in terms of the structure factor $S({bf k})$, which is especially useful when scattering information is available experimentally or theoretically. We show that the free-volume theory of the pressure of equilibrium packings of identical hard spheres that approach a strictly jammed state either along the stable crystal or metastable disordered branch dictates that such end states be exactly hyperuniform. Using the ratio $B/A$, the hyperuniformity index $H$ and the direct-correlation function length scale $xi_c$, we study three different exactly solvable models as a function of the relevant control parameter, either density or temperature, with end states that are perfectly hyperuniform. We analyze equilibrium hard rods and sticky hard-sphere systems in arbitrary space dimension $d$ as a function of density. We also examine low-temperature excited states of many-particle systems interacting with stealthy long-ranged pair interactions as the temperature tends to zero. The capacity to identify hyperuniform scaling regimes should be particularly useful in analyzing experimentally- or computationally-generated samples that are necessarily of finite size.
Within the framework of the Helfrich elastic theory of membranes and of differential geometry we study the possible instabilities of spherical vesicles towards double bubbles. We find that not only temperature, but also magnetic fields can induce topological transformations between spherical vesicles and double bubbles and provide a phase diagram for the equilibrium shapes.
Granulation is a ubiquitous process crucial for many products ranging from food and care products to pharmaceuticals. Granulation is the process in which a powder is mixed with a small amount of liquid (binder) to form solid agglomerates surrounded by air. By contrast, at low solid volume fractions {phi}, the mixing of solid and liquid produces suspensions. At intermediate {phi}, either granules or dense suspensions are produced, depending on the applied stress. We address the question of how and when high shear mixing can lead to the formation of jammed, non-flowing granules as {phi} is varied. In particular, we measure the shear rheology of a model system - a suspension of glass beads with an average diameter of $sim$ 7 {mu}m - at solid volume fractions {phi} $gtrsim$ 0.40. We show that recent insights into the role of inter-particle friction in suspension rheology allow us to use flow data to predict some of the boundaries between different types of granulation as {phi} increases from $sim$ 0.4 towards and beyond the maximum packing point of random close packing.
Polymer-grafted nanoparticles (PGNPs) can provide property profiles than cannot be obtained individually by polymers or nanoparticles (NPs). Here, we have studied the mixing--demixing transition of symmetric copolymer melts of polymer-grafted spherical nanoparticles by means of coarse-grained molecular dynamics simulation and a theoretical mean-field model. We find that a larger size of NPs leads to higher stability for given number of grafted chains and chain length reaching a point where demixing is not possible. Most importantly, the increase in the number of grafted chains, $N_g$, can initially favour the phase separation of PGNPs, but further increase can lead to more difficult demixing. The reason is the increasing impact of an effective core that forms as the grafting density of the tethered polymer chains around the NPs increases. The range and exact values of $N_g$ where this change in behaviour takes place depends on the NP size and the chain length of the grafted polymer chains. Our study elucidates the phase behaviour of PGNPs and in particular the influence of the grafting density on the phase behaviour of the systems anticipating that it will open new doors in the understanding of these systems with implications in materials science and medicine.