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We report column densities of molecular gas in the W5 star-forming region as traced with OH 18-cm emission in a grid survey using the Green Bank Telescope. OH appears to trace a greater column density than does CO in 8 out of 15 cases containing OH emission detections; the two molecules trace the same column densities for the other 7 cases. OH and CO trace a similar morphology of molecular gas with a nearly one-to-one correspondence. The mass of molecular gas traced by OH in the portion of the survey containing OH emission is $1.7$ (+ 0.6 or - 0.2) $times 10^4 M_{odot}$, whereas the corresponding CO detections trace $9.9 times 10^3 M_{odot} (pm 0.7) times 10^3$. We find that for lines observed in absorption, calculations assuming uniform gas and continuum distributions underestimate column density values by 1 to 2 orders of magnitude, making them unreliable for our purposes. Modeling of this behavior in terms of OH cloud structure on a scale smaller than telescopic resolution leads us to estimate that the filling factor of OH gas is a few to 10 percent. Consideration of filling factor effects also results in a method of constraining the excitation temperature values. The total molecular gas content of W5 may be approximately two to three times what we report from direct measurement, because we excluded absorption line detections from the mass estimate.
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We present excitation temperatures $T_{ex}$ for the OH 18-cm main lines at 1665 and 1667 MHz measured directly in front of the W5 star-forming region, using observations from the Green Bank Telescope and the Very Large Array. We find unequivocally that $T_{ex}$ at 1665 MHz is greater than $T_{ex}$ at 1667 MHz. Our method exploits variations in the continuum emission from W5, and the fact that the continuum brightness temperatures $T_C$ in this nebula are close to the excitation temperatures of the OH lines in the foreground gas. The result is that an OH line can appear in emission in one location and in absorption in a neighboring location, and the value of $T_C$ where the profiles switch from emission to absorption indicates $T_{ex}$. Absolute measurements of $T_{ex}$ for the main lines were subject to greater uncertainty because of unknown effects of geometry of the OH features. We also employed the traditional expected profile method for comparison with our continuum background method, and found that the continuum background method provided more precise results, and was the one to definitively show the $T_{ex}$ difference. Our best estimate values are: $T^{65}_{ex} = 6.0 pm 0.5$ K, $T^{67}_{ex} = 5.1 pm 0.2$ K, and $T^{65}_{ex} - T^{67}_{ex} = 0.9 pm 0.5$ K. The $T_{ex}$ values we have measured for the ISM in front of W5 are similar to those found in the quiescent ISM, indicating that proximity to massive star-forming regions does not generally result in widespread anomalous excitation of OH emission.
Trends observed in galaxies, such as the Gao & Solomon relation, suggest a linear relation between the star formation rate and the mass of dense gas available for star formation. Validation of such relations requires the establishment of reliable methods to trace the dense gas in galaxies. One frequent assumption is that the HCN ($J=1$--0) transition is unambiguously associated with gas at $rm{}H_2$ densities $gg{}10^4~rm{}cm^{-3}$. If so, the mass of gas at densities $gg{}10^4~rm{}cm^{-3}$ could be inferred from the luminosity of this emission line, $L_{rm{}HCN,(1text{--}0)}$. Here we use observations of the Orion~A molecular cloud to show that the HCN ($J=1$--0) line traces much lower densities $sim{}10^3~rm{}cm^{-3}$ in cold sections of this molecular cloud, corresponding to visual extinctions $A_Vapprox{}6~rm{}mag$. We also find that cold and dense gas in a cloud like Orion produces too little HCN emission to explain $L_{rm{}HCN,(1text{--}0)}$ in star--forming galaxies, suggesting that galaxies might contain a hitherto unknown source of HCN emission. In our sample of molecules observed at frequencies near 100~GHz (also including $rm{}^{12}CO$, $rm{}^{13}CO$, $rm{}C^{18}O$, CN, and CCH), $rm{}N_2H^+$ is the only species clearly associated with rather dense gas.
We present synthetic Hi and CO observations of a simulation of decaying turbulence in the thermally bistable neutral medium. We first present the simulation, with clouds initially consisting of clustered clumps. Self-gravity causes these clump clusters to form more homogeneous dense clouds. We apply a simple radiative transfer algorithm, and defining every cell with <Av> > 1 as molecular. We then produce maps of Hi, CO-free molecular gas, and CO, and investigate the following aspects: i) The spatial distribution of the warm, cold, and molecular gas, finding the well-known layered structure, with molecular gas surrounded by cold Hi, surrounded by warm Hi. ii) The velocity of the various components, with atomic gas generally flowing towards the molecular gas, and that this motion is reflected in the frequently observed bimodal shape of the Hi profiles. This conclusion is tentative, because we do not include feedback. iii) The production of Hi self-absorption (HISA) profiles, and the correlation of HISA with molecular gas. We test the suggestion of using the second derivative of the brightness temperature Hi profile to trace HISA and molecular gas, finding limitations. On a scale of ~parsecs, some agreement is obtained between this technique and actual HISA, as well as a correlation between HISA and N(mol). It quickly deteriorates towards sub-parsec scales. iv) The N-PDFs of the actual Hi gas and those recovered from the Hi line profiles, with the latter having a cutoff at column densities where the gas becomes optically thick, thus missing the contribution from the HISA-producing gas. We find that the power-law tail typical of gravitational contraction is only observed in the molecular gas, and that, before the power-law tail develops in the total gas density PDF, no CO is yet present, reinforcing the notion that gravitational contraction is needed to produce this component. (abridged)
The oxygen-bearing molecular ions OH+, H2O+, and H3O+ are key species that probe the ionization rate of (partially) molecular gas that is ionized by X-rays and cosmic rays permeating the interstellar medium. We report Herschel far-infrared and submillimeter spectroscopic observations of OH+ in Mrk 231, showing both ground-state P-Cygni profiles, and excited line profiles with blueshifted absorption wings extending up to ~1000 km s^{-1}. In addition, OH+ probes an excited component peaking at central velocities, likely arising from the torus probed by the OH centimeter-wave megamaser. Four lines of H2O+ are also detected at systemic velocities, but H3O+ is undetected. Based on our earlier OH studies, we estimate an abundance ratio of OH/OH+~5-10 for the outflowing components and ~20 for the torus, and an OH+ abundance relative to H nuclei of ~>10^{-7}. We also find high OH+/H2O+ and OH+/H3O+ ratios, both are ~>4 in the torus and ~>10-20 in the outflowing gas components. Chemical models indicate that these high OH+ abundances relative to OH, H2O+, and H3O+ are characteristic of gas with a high ionization rate per unit density, zeta/n_H~(1-5)x10^{-17} cm^3 s^{-1} and ~(1-2)x10^{-16} cm^3 s^{-1} for the above components, respectively, and an ionization rate of zeta~(0.5-2)x10^{-12} s^{-1}. X-rays appear to be unable to explain the inferred ionization rate, and thus we suggest that low-energy (10-400 MeV) cosmic-rays are primarily responsible for the ionization with dot{M}_{CR}~0.01 M_{sun} yr^{-1} and dot{E}_{CR}~10^{44} erg s^{-1}, the latter corresponding to 1% of the AGN luminosity and similar to the energetics of the molecular outflow. We suggest that cosmic-rays accelerated in the forward shock associated with the molecular outflow are responsible for the ionization, as they diffuse through the outflowing molecular phase downstream.
We discuss the detection of absorption by interstellar hydrogen fluoride (HF) along the sight line to the submillimeter continuum sources W49N and W51. We have used Herschels HIFI instrument in dual beam switch mode to observe the 1232.4762 GHz J = 1 - 0 HF transition in the upper sideband of the band 5a receiver. We detected foreground absorption by HF toward both sources over a wide range of velocities. Optically thin absorption components were detected on both sight lines, allowing us to measure - as opposed to obtain a lower limit on - the column density of HF for the first time. As in previous observations of HF toward the source G10.6-0.4, the derived HF column density is typically comparable to that of water vapor, even though the elemental abundance of oxygen is greater than that of fluorine by four orders of magnitude. We used the rather uncertain N(CH)-N(H2) relationship derived previously toward diffuse molecular clouds to infer the molecular hydrogen column density in the clouds exhibiting HF absorption. Within the uncertainties, we find that the abundance of HF with respect to H2 is consistent with the theoretical prediction that HF is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen fluoride has the potential to become an excellent tracer of molecular hydrogen, and provides a sensitive probe of clouds of small H2 column density. Indeed, the observations of hydrogen fluoride reported here reveal the presence of a low column density diffuse molecular cloud along the W51 sight line, at an LSR velocity of ~ 24kms-1, that had not been identified in molecular absorption line studies prior to the launch of Herschel.
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