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H. Nikolic
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We formulate Bohmian mechanics (BM) such that the main objects of concern are macroscopic phenomena, while microscopic particle trajectories only play an auxiliary role. Such a formulation makes it easy to understand why BM always makes the same measurable predictions as standard quantum mechanics (QM), irrespectively of the details of microscopic trajectories. Relativistic quantum field theory (QFT) is interpreted as an effective long-distance theory that at smaller distances must be replaced by some more fundamental theory. Analogy with condensed-matter physics suggests that this more fundamental theory could have a form of non-relativistic QM, offering a simple generic resolution of an apparent conflict between BM and relativistic QFT.
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It is shown that quantum entanglement is the only force able to maintain the fourth state of matter, possessing fixed shape at an arbitrary volume. Accordingly, a new relativistic Schrodinger equation is derived and transformed further to the relativistic Bohmian mechanics via the Madelung transformation. Three dissipative models are proposed as extensions of the quantum relativistic Hamilton-Jacobi equation. The corresponding dispersion relations are obtained.
Bohmian mechanics (BM) draws a picture of nature, which is completely different from that drawn by standard quantum mechanics (SQM): Particles are at any time at a definite position, and the universe evolves deterministically. Astonishingly, according to a proof by Bohm the empirical predictions of these two very different theories coincide. From the very beginning, BM has faced all kinds of criticism, most of which are either technical or philosophical. There is, however, a criticism first raised by Correggi et al. (2002) and recently strengthened by Kiukas and Werner (2010), which holds that, in spite of Bohms proof, the predictions of BM do not agree with those of SQM in the case of local position measurements on entangled particles in a stationary state. Hence, given that SQM has been proven to be tremendously successful in the past, BM could most likely not be considered an empirically adequate theory. My aim is to resolve the conflict by showing that 1) it relies on hidden differences in the conceptual thinking, and that 2) the predictions of both theories approximately coincide if the process of measurement is adequately accounted for. My analysis makes no use of any sort of wavefunction collapse, refuting a widespread belief that an effective collapse is needed to reconcile BM with the predictions of SQM.
Bohmian mechanics is a causal interpretation of quantum mechanics in which particles describe trajectories guided by the wave function. The dynamics in the vicinity of nodes of the wave function, usually called vortices, is regular if they are at rest. However, vortices generically move during time evolution of the system. We show that this movement is the origin of chaotic behavior of quantum trajectories. As an example, our general result is illustrated numerically in the two-dimensional isotropic harmonic oscillator.
We develop an extension of Bohmian mechanics to a curved background space-time containing a singularity. The present paper focuses on timelike singularities. We use the naked timelike singularity of the super-critical Reissner-Nordstrom geometry as an example. While one could impose boundary conditions at the singularity that would prevent the particles from falling into the singularity, we are interested here in the case in which particles have positive probability to hit the singularity and get annihilated. The wish for reversibility, equivariance, and the Markov property then dictates that particles must also be created by the singularity, and indeed dictates the rate at which this must occur. That is, a stochastic law prescribes what comes out of the singularity. We specify explicit equations of a non-rigorous model involving an interior-boundary condition on the wave function at the singularity, which can be used also in oth
Perhaps because of the popularity that trajectory-based methodologies have always had in Chemistry and the important role they have played, Bohmian mechanics has been increasingly accepted within this community, particularly in those areas of the theoretical chemistry based on quantum mechanics, e.g., quantum chemistry, chemical physics, or physical chemistry. From a historical perspective, this evolution is remarkably interesting, particularly when the scarce applications of Madelungs former hydrodynamical formulation, dating back to the late 1960s and the 1970s, are compared with the many different applications available at present. As also happens with classical methodologies, Bohmian trajectories are essentially used to described and analyze the evolution of chemical systems, to design and implement new computational propagation techniques, or a combination of both. In the first case, Bohmian trajectories have the advantage that they avoid invoking typical quantum-classical correspondence to interpret the corresponding phenomenon or process, while in the second case quantum-mechanical effects appear by themselves, without the necessity to include artificially quantization conditions. Rather than providing an exhaustive revision and analysis of all these applications (excellent monographs on the issue are available in the literature for the interested reader, which can be consulted in the bibliography here supplied), this Chapter has been prepared in a way that it may serve the reader to acquire a general view (or impression) on how Bohmian mechanics has permeated the different traditional levels or pathways to approach molecular systems in Chemistry: electronic structure, molecular dynamics and statistical mechanics. This is done with the aid of some illustrative examples -- theoretical developments in some cases and numerical simulations in other cases.
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