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Register a new userMechanism of superconductivity and electron-hole doping asymmetry in $kappa$-type molecular conductors
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Unconventional superconductivity in molecular conductors is observed at the border of metal-insulator transitions in correlated electrons under the influence of geometrical frustration. The symmetry as well as the mechanism of the superconductivity (SC) is highly controversial. To address this issue, we theoretically explore the electronic properties of carrier-doped molecular Mott system $kappa$-(BEDT-TTF)$_2$X. We find significant electron-hole doping asymmetry in the phase diagram where antiferromagnetic (AF) spin order, different patterns of charge order, and SC compete with each other. Hole-doping stabilizes AF phase and promotes SC with $d_{xy}$-wave symmetry, which has similarities with high-$T_c$ cuprates. In contrast, in the electron-doped side, geometrical frustration destabilizes the AF phase and the enhanced charge correlation induces another SC with extended-$s$+$d_{x^2-y^2}$-wave symmetry. Our results disclose the mechanism of each phase appearing in filling-control molecular Mott systems, and elucidate how physics of different strongly-correlated electrons are connected, namely, molecular conductors and high-$T_c$ cuprates.
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We generalize the theory of Cooper pairing by spin excitations in the metallic antiferromagnetic state to include situations with electron and/or hole pockets. We show that Cooper pairing arises from transverse spin waves and from gapped longitudinal spin fluctuations of comparable strength. However, each of these interactions, projected on a particular symmetry of the superconducting gap, acts primarily within one type of pocket. We find a nodeless $d_{x^2-y^2}$-wave state is supported primarily by the longitudinal fluctuations on the electron pockets, and both transverse and longitudinal fluctuations support nodeless odd-parity spin singlet $p-$wave symmetry on the hole pockets. Our results may be relevant to the asymmetry of the AF/SC coexistence state in the cuprate phase diagram, as well as for the nodal gap observed recently for strongly underdoped cuprates.
High-temperature superconductivity (HTSC) mysteriously emerges upon doping holes or electrons into insulating copper oxides with antiferromagnetic (AFM) order. It has been thought that the large energy scale of magnetic excitations, compared to phonon energies for example, lies at the heart of an electronically-driven superconducting phase at high temperatures. However, despite extensive studies, little information is available for comparison of high-energy magnetic excitations of hole- and electron-doped superconductors to assess a possible correlation with the respective superconducting transition temperatures. Here, we use resonant inelastic x-ray scattering (RIXS) at the Cu L3-edge to reveal high-energy collective excitations in the archetype electron-doped cuprate Nd2-xCexCuO4 (NCCO). Surprisingly, despite the fact that the spin stiffness is zero and the AFM correlations are short-ranged, magnetic excitations harden significantly across the AFM-HTSC phase boundary, in stark contrast with the hole-doped cuprates. Furthermore, we find an unexpected and highly dispersive mode in superconducting NCCO that is undetected in the hole-doped compounds, which emanates from the zone center with a characteristic energy comparable to the pseudogap, and may signal a quantum phase distinct from superconductivity. The uncovered asymmetry in the high-energy collective excitations with respect to hole and electron doping provides additional constraints for modeling the HTSC cuprates.
We show, from first-principles calculations, that the hole-doped side of FeAs-based compounds is different from its electron-doped counterparts. The electron side is characterized as Fermi surface nesting, and SDW-to-NM quantum critical point (QCP) is realized by doping. For the hole-doped side, on the other hand, orbital-selective partial orbital ordering develops together with checkboard antiferromagnetic (AF) ordering without lattice distortion. A unique SDW-to-AF QCP is achieved, and $J_2$=$J_1/2$ criteria (in the approximate $J_1&J_2$ model) is satisfied. The observed superconductivity is located in the vicinity of QCP for both sides.
We discuss evolution of the Fermi surface (FS) topology with doping in electron doped cuprates within the framework of a one-band Hubbard Hamiltonian, where antiferromagnetism and superconductivity are assumed to coexist in a uniform phase. In the lightly doped insulator, the FS consists of electron pockets around the $(pi,0)$ points. The first change in the FS topology occurs in the optimally doped region when an additional hole pocket appears at the nodal point. The second change in topology takes place in the overdoped regime ($sim18%$) where antiferromagnetism disappears and a large $(pi,pi)$-centered metallic FS is formed. Evidence for these two topological transitions is found in recent Hall effect and penetration depth experiments on Pr$_{2-x}$Ce$_{x}$CuO$_{4-delta}$ (PCCO) and with a number of spectroscopic measurements on Nd$_{2-x}$Ce$_{x}$CuO$_{4-delta}$ (NCCO).
The discovery of EuFeAs2, currently the only charge-neutral parent phase of the 112-type iron-pnictide system, provides a new platform for the study of elemental doping effects on magnetism and superconductivity (SC). In this study, a series of polycrystalline EuFe1-yCoyAs2 and Eu0.9Pr0.1Fe1-yCoyAs2 samples are synthesized through solid-state reaction, and the evolutions of SC and magnetism with Co doping in EuFeAs2 and Eu0.9Pr0.1FeAs2 are investigated by electrical transport and magnetic susceptibility measurements. For EuFe1-yCoyAs2, the Eu-related antiferromagnetic (AFM) transition around 40 K is barely affected by Co doping, while the Fe-related spin density wave (SDW) transition temperature drops rapidly. Meanwhile, SC is induced by a trace amount of Co doping, with a highest transition temperature Tc ~ 28 K found in EuFe0.9Co0.1As2. For the Eu0.9Pr0.1Fe1-yCoyAs2 series, the magnetism and superconductivity show similar evolutions upon Co doping, and the highest Tc is enhanced to 30.6 K with an optimum doping level y ~ 0.07. Our results shed light on the competition between SC and SDW with Co doping in the 112-type EuFeAs2 system.
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