Abstract We perform an experiment in which a quantum heat engine works under two reservoirs, one at a positive spin temperature and the other at an effective negative spin temperature i.e., when the spin system presents population inversion. We show that the efficiency of this engine can be greater than that when both reservoirs are at positive temperatures. We also demonstrate the counter-intuitive result that the Otto efficiency can be beaten only when the quantum engine is operating in the finite-time mode.
Recent theoretical and experimental studies in quantum heat engines show that, in the quasi-static regime, it is possible to have higher efficiency than the limit imposed by Carnot, provided that engineered reservoirs are used. The quasi-static regime, however, is a strong limitation to the operation of heat engines, since infinitely long time is required to complete a cycle. In this paper we propose a two-level model as the working substance to perform a quantum Otto heat engine surrounded by a cold thermal reservoir and a squeezed hot thermal reservoir. Taking advantage of this model we show a striking achievement, that is to attain unity efficiency even at non null power.
We derive the probability distribution of the efficiency of a quantum Otto engine. We explicitly compute the quantum efficiency statistics for an analytically solvable two-level engine. We analyze the occurrence of values of the stochastic efficiency above unity, in particular at infinity, in the nonadiabatic regime and further determine mean and variance in the case of adiabatic driving. We finally investigate the classical-to-quantum transition as the temperature is lowered.
The second law of thermodynamics constrains that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasi-probability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the $hbar$-dependent quantum mechanical bound for the efficiency. It turns out that the bound is tighter than the Carnot efficiency. The engine achieves the bound in the low temperature limit where quantum effects dominate. Our work demonstrates that quantum nature could suppress the performance of heat engines in terms of efficiency bound, work and power output.
We study an Otto heat machine whose working substance is a single two-level system interacting with a cold thermal reservoir and with a squeezed hot thermal reservoir. By adjusting the squeezing or the adiabaticity parameter (the probability of transition) we show that our two-level system can function as a universal heat machine, either producing net work by consuming heat or consuming work that is used to cool or heat environments. Using our model we study the performance of these machine in the finite-time regime of the isentropic strokes, which is a regime that contributes to make them useful from a practical point of view.
Cyclical heat engines are a paradigm of classical thermodynamics, but are impractical for miniaturization because they rely on moving parts. A more recent concept is particle-exchange (PE) heat engines, which uses energy filtering to control a thermally driven particle flow between two heat reservoirs. As they do not require moving parts and can be realized in solid-state materials, they are suitable for low-power applications and miniaturization. It was predicted that PE engines could reach the same thermodynamically ideal efficiency limits as those accessible to cyclical engines, but this prediction has not been verified experimentally. Here, we demonstrate a PE heat engine based on a quantum dot (QD) embedded into a semiconductor nanowire. We directly measure the engines steady-state electric power output and combine it with the calculated electronic heat flow to determine the electronic efficiency $eta$. We find that at the maximum power conditions, $eta$ is in agreement with the Curzon-Ahlborn efficiency and that the overall maximum $eta$ is in excess of 70$%$ of the Carnot efficiency while maintaining a finite power output. Our results demonstrate that thermoelectric power conversion can, in principle, be achieved close to the thermodynamic limits, with direct relevance for future hot-carrier photovoltaics, on-chip coolers or energy harvesters for quantum technologies.
Rogerio J. de Assis
,Taysa M. de Mendonc{c}a
,Celso J. Villas-Boas
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(2018)
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"Efficiency of a quantum Otto heat engine operating under a reservoir at effective negative temperatures"
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Norton G. de Almeida Dr.
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