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Register a new userThree heats in strongly coupled system and bath
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We investigate three kinds of heat produced in a system and a bath strongly coupled via an interaction Hamiltonian. By studying the energy flows between the system, the bath, and their interaction, we provide rigorous definitions of two types of heat, $Q_{rm S}$ and $Q_{rm B}$ from the energy loss of the system and the energy gain of the bath, respectively. This is in contrast to the equivalence of $Q_{rm S}$ and $Q_{rm B}$, which is commonly assumed to hold in the weak coupling regime. The bath we consider is equipped with a thermostat which enables it to reach an equilibrium. We identify another kind of heat $Q_{rm SB}$ from the energy dissipation of the bath into the super bath that provides the thermostat. We derive the fluctuation theorems (FTs) with the system variables and various heats, which are discussed in comparison with the FT for the total entropy production. We take an example of a sliding harmonic potential of a single Brownian particle in a fluid and calculate the three heats in a simplified model. These heats are found to equal on average in the steady state of energy, but show different fluctuations at all times.
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Bistable systems present two degenerate metastable configurations separated by an energy barrier. Thermal or quantum fluctuations can promote the transition between the configurations at a rate which depends on the dynamical properties of the local environment (i.e., a thermal bath). In the case of classical systems, strong system-bath interaction has been successfully modelled by the Generalised Langevin Equation (GLE) formalism. Here we show that the efficient GLE algorithm introduced in Phys. Rev. B 89, 134303 (2014) can be extended to include some crucial aspects of the quantum fluctuations. In particular, the expected isotopic effect is observed along with the convergence of the quantum and classical transition rates in the strong coupling limit. Saturation of the transition rates at low temperature is also retrieved, in qualitative, yet not quantitative, agreement with the analytic predictions. The discrepancies in the tunnelling regime are due to an incorrect sampling close to the barrier top. The domain of applicability of the quasiclassical GLE is also discussed.
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Understanding non-equilibrium heat transport is crucial for controling heat flow in nano-scale systems. We study thermal energy transfer in a generalized non-equilibrium spin-boson model (NESB) with non-commutative system-bath coupling operators and discover unusual transport properties. Compared to the conventional NESB, the heat current is greatly enhanced by rotating the coupling operators. Constructive contribution to thermal rectification can be optimized when two sources of asymmetry, system-bath coupling strength and coupling operators, coexist. At the weak coupling and the adiabatic limit, the scaling dependence of heat current on the coupling strength and the system energy gap changes drastically when the coupling operators become non-commutative. These scaling relations can further be explained analytically by the non-equilibrium polaron-transformed Redfield equation. These novel transport properties, arising from the pure quantum effect of non-commutative coupling operators, should generally appear in other non-equilibrium set-ups and driven-systems.
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