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Register a new userThe census of interstellar complex organic molecules in the Class I hot corino of SVS13-A
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We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an high-sensitivity unbiased spectral survey at the 1mm, 2mm and 3mm IRAM bands. We detected five iCOMs: acetaldehyde (CH$_3$CHO), methyl formate (HCOOCH$_3$), dimethyl ether (CH$_3$OCH$_3$), ethanol (CH$_3$CH$_2$OH) and formamide (NH$_2$CHO). In addition we searched for other iCOMs and ketene (H$_2$CCO), formic acid (HCOOH) and methoxy (CH$_3$O), whose only ketene was detected. The numerous detected lines, from 5 to 37 depending on the species, cover a large upper level energy range, between 15 and 254 K. This allowed us to carry out a rotational diagram analysis and derive rotational temperatures between 35 and 110 K, and column densities between $3times 10^{15}$ and $1times 10^{17}$ cm$^{-2}$ on the 0.3 size previously determined by interferometric observations of glycolaldehyde. These new observations clearly demonstrate the presence of a rich chemistry in the hot corino towards SVS13-A. The measured iCOMs abundances were compared to other Class 0 and I hot corinos, as well as comets, previously published in the literature. We find evidence that (i) SVS13-A is as chemically rich as younger Class 0 protostars, and (ii) the iCOMs relative abundances do not substantially evolve during the protostellar phase.
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The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which, therefore, represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA Large Program FAUST. We detected several lines from methanol and its isopotologues ($^{13}$CH$_{rm 3}$OH and CH$_{rm 2}$DOH), methyl formate and ethanol. Lines are bright toward the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines non-LTE analysis constrains the gas temperature ($sim$100 K), density ($geq$1.5$times$10$^{8}$ cm$^{-3}$), and emitting size ($sim$10 au in radius). All CH$_{rm 3}$OH and $^{13}$CH$_{rm 3}$OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on the present work, little chemical evolution from Class 0 to I hot corinos occurs.
We report the first evidence of a hot corino in a Bok globule. This is based on the ALMA observations in the 1.2 mm band toward the low-mass Class 0 protostar IRAS 19347+0727 in B335. Saturated complex organic molecules (COMs), CH$_3$CHO, HCOOCH$_3$, and NH$_2$CHO, are detected in a compact region within a few 10 au around the protostar. Additionally, CH$_3$OCH$_3$, C$_2$H$_5$OH, C$_2$H$_5$CN, and CH$_3$COCH$_3$ are tentatively detected. Carbon-chain related molecules, CCH and c-C$_3$H$_2$, are also found in this source, whose distributions are extended over a few 100 au scale. On the other hand, sulfur-bearing molecules CS, SO, and SO$_2$, have both compact and extended components. Fractional abundances of the COMs relative to H$_2$ are found to be comparable to those in known hot-corino sources. Though the COMs lines are as broad as 5-8 km s$^{-1}$, they do not show obvious rotation motion in the present observation. Thus, the COMs mainly exist in a structure whose distribution is much smaller than the synthesized beam (0.58 x 0.52).
Aims: A unique environment to study how interstellar Complex Organic Molecules (iCOMs) can be formed is the shocked gas along low-mass protostellar outflows, as the dust mantles composition is sputtered into the gas phase. The chemical richness in these environments has been so far studied only in the L1157 blue shifted outflow. Methods: To understand if the L1157-B1 case is unique, we imaged the NGC 1333 IRAS 4A outflows using the NOEMA (NOrthern Extended Millimeter Array) interferometer as part of the IRAM SOLIS (Seeds Of Life in Space) Large Program and compared the observations with the GRAINOBLE+ gas phase astrochemical model. Results: Several iCOMs were detected in the IRAS 4A outflows: methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), formamide (NH$_2$CHO) and dimethyl ether (CH$_3$OCH$_3$), all sampling upper excitation energy up to $sim$30 K. We found a significant chemical differentiation between the IRAS 4A1 outflow, showing a richer molecular content, and the IRAS 4A2 one. The CH$_3$OH/CH$_3$CHO abundance ratio is lower by a factor $sim$4 in the former; furthermore the ratio in both outflows is lower by a factor $sim$10 with respect to hot corinos values. Conclusions: After L1157-B1, IRAS 4A outflow is now the second outflow to show an evident chemical complexity. Given that CH$_3$OH is a grain surface species, GRAINOBLE+ reproduced our observations assuming acetaldehyde formation in gas phase by the reaction of ethyl radical (CH$_3$CH$_2$) with atomic oxygen. Moreover, the chemical differentiation between the two outflows suggests that the IRAS 4A1 outflow is likely younger than the IRAS 4A2 one. Further investigation is needed to constrain the age of the outflow and observations of even younger shocks are necessary and future spectroscopic studies on CH$_3$CH$_2$ are needed to be able to observe this species and provide strong constraints on the CH$_3$CHO formation.
The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry at low temperatures has provided new insight into these processes predicting that COM formation depends strongly on parameters such as visual extinction and the level of CO freeze out. We report deep observations of COMs toward two positions in the L1544 pre-stellar core: the dense, highly-extinguished continuum peak with Av>=30 mag within the inner 2700 au; and a low-density shell with average Av~7.5-8 mag located at 4000 au from the cores center and bright in CH3OH. Our observations show that CH3O, CH3OCH3 and CH3CHO are more abundant (by factors ~2-10) toward the low-density shell than toward the continuum peak. Other COMs such as CH3OCHO, c-C3H2O, HCCCHO, CH2CHCN and HCCNC show slight enhancements (by factors <=3) but the associated uncertainties are large. This suggests that COMs are actively formed and already present in the low-density shells of pre-stellar cores. The modelling of the chemistry of O-bearing COMs in L1544 indicates that these species are enhanced in this shell because i) CO starts freezing out onto dust grains driving an active surface chemistry; ii) the visual extinction is sufficiently high to prevent the UV photo-dissociation of COMs by the external interstellar radiation field; and iii) the density is still moderate to prevent severe depletion of COMs onto grains.
We present the results of formaldehyde and methanol deuteration measurements towards the Class I low-mass protostar SVS13-A, in the framework of the IRAM 30-m ASAI (Astrochemical Surveys At IRAM) project. We detected emission lines of formaldehyde, methanol, and their deuterated forms (HDCO, D2CO, CHD2OH, CH3OD) with Eup up to 276 K. The formaldehyde analysis indicates Tkin = 15 - 30 K, n (H2) >= 10^6 cm^-3, and a size of about 1200 AU suggesting an origin in the protostellar envelope. For methanol we find two components: (i) a high temperature (Tkin = 80 K) and very dense (> 10^8 cm^-3}) gas from a hot corino (radius about 35 AU), and (ii) a colder Tkin <= 70 K) and more extended (radius about 350 AU) region. The deuterium fractionation is 9 10^-2 for HDCO, 4 10^-3 for D2CO, and 2 - 7 10^-3 for CH2DOH, up to two orders of magnitude lower than the values measured in Class 0 sources. We derive also formaldehyde deuteration in the outflow: 4 10^-3, in agreement with what found in the L1157-B1 protostellar shock. Finally, we estimate [CH2DOH]/[CH3OD] about 2. The decrease of deuteration in the Class I source SVS13-A with respect to Class 0 sources can be explained by gas-phase processes. Alternatively, a lower deuteration could be the effect of a gradual collapse of less deuterated external shells of the protostellar evelope. The present measurements fill in the gap between prestellar cores and protoplanetary disks in the context of organics deuteration measurements.
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