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Register a new userO2 signature in thin and thick O2-H2O ices
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Added by
Birgitta M\\\"uller
Publication date
2018
fields
Physics
and research's language is
English
Authors
B. Muller
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Aims. In this paper we investigate the detectability of the molecular oxygen in icy dust grain mantles towards astronomical objects. Methods. We present a systematic set of experiments with O2-H2O ice mixtures designed to disentangle how the molecular ratio affects the O2 signature in the mid- and near-infrared spectral regions. All the experiments were conducted in a closed-cycle helium cryostat coupled to a Fourier transform infrared spectrometer. The ice mixtures comprise varying thicknesses from 8 $times$ 10$^{-3}$ to 3 $mu$m. The absorption spectra of the O2-H2O mixtures are also compared to the one of pure water. In addition, the possibility to detect the O2 in icy bodies and in the interstellar medium is discussed. Results. We are able to see the O2 feature at 1551 cm$^{-1}$ even for the most diluted mixture of H2O : O2 = 9 : 1, comparable to a ratio of O2/H2O = 10 % which has already been detected in situ in the coma of the comet 67P/Churyumov-Gerasimenko. We provide an estimate for the detection of O2 with the future mission of the James Webb Space Telescope (JWST).
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Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV fluxes are high. N2 and O2 are expected to play key roles in astrochemical reaction networks, both in the solid state and in the gas phase. Measurements of the wavelength-dependent photodesorption rates of these two infrared-inactive molecules provide astronomical and physical-chemical insights into the conditions required for their photodesorption. Tunable radiation from the DESIRS beamline at the SOLEIL synchrotron in the astrophysically relevant 7 to 13.6 eV range is used to irradiate pure N2 and O2 thin ice films. Photodesorption of molecules is monitored through quadrupole mass spectrometry. Absolute rates are calculated by using the well-calibrated CO photodesorption rates. Strategic N2 and O2 isotopolog mixtures are used to investigate the importance of dissociation upon irradiation. N2 photodesorption mainly occurs through excitation of the b^1Pi_u state and subsequent desorption of surface molecules. The observed vibronic structure in the N2 photodesorption spectrum, together with the absence of N3 formation, supports that the photodesorption mechanism of N2 is similar to CO, i.e., an indirect DIET (Desorption Induced by Electronic Transition) process without dissociation of the desorbing molecule. In contrast, O2 photodesorption in the 7 - 13.6 eV range occurs through dissociation and presents no vibrational structure. Photodesorption rates of N2 and O2 integrated over the far-UV field from various star-forming environments are lower than for CO. Rates vary between 10E-3 and 10E-2 photodesorbed molecules per incoming photon.
We present the detection of molecular oxygen with Odin toward the dense molecular core rho Oph A, which is part of a region of active star formation. The observed spectral line is the (N,J = 1,1-1,0) ground state transition of molecular oxygen at 119 GHz (2.5 mm wavelength). The center of the line is at the LSR velocity of a number of optically thin lines from other species in the region and the O2 line also has a very similar, narrow, line width. Within the 10 arcmin beam, the integrated line intensity is 28 mK km/s, which corresponds to 5 sigma of the rms noise. A standard LTE analysis results in an O2 abundance of 5E(-8), with an uncertainty of at least a factor of two. We show that standard methods, however, do not apply in this case, as the coupling of the Odin beam to the source structure needs to be accounted for. Preliminary model results indicate O2 abundances to be higher by one order of magnitude than suggested by the standard case. This model predicts the 487 GHz line of O2 to be easily detectable by the future Herschel-HIFI facility, but to be out of reach for observations on a shorter time scale with the Odin space observatory.
We compute the circularly polarized signal from atmospheric molecular oxygen. Polarization of O2 rotational lines is caused by Zeeman effect in the Earth magnetic field. We evaluate the circularly polarized emission for various sites suitable for CMB measurements: South Pole and Dome C (Antarctica), Atacama (Chile) and Testa Grigia (Italy). An analysis of the polarized signal is presented and discussed in the framework of future CMB polarization experiments. We find a typical circularly polarized signal (V Stokes parameter) of ~ 50 - 300 {mu}K at 90 GHz looking at the zenith. Among the other sites Atacama shows the lower polarized signal at the zenith. We present maps of this signal for the various sites and show typical elevation and azimuth scans. We find that Dome C presents the lowest gradient in polarized temperature: ~ 0.3 {mu}K/circ at 90 GHz. We also study the frequency bands of observation: around { u} simeq 100 GHz and { u} simeq 160 GHz we find the best conditions because the polarized signal vanishes. Finally we evaluate the accuracy of the templates and the signal variability in relation with the knowledge and the variability of the Earth magnetic field and the atmospheric parameters.
Environmental research aimed at monitoring and predicting O2 depletion is still lacking or in need of improvement, in spite of many attempts to find a relation between atmospheric gas content and climate variability. The aim of the present project is to determine accurate historical sequences of the atmospheric O2 depletion by using the telluric lines present in stellar spectra. A better understanding of the role of oxygen in atmospheric thermal equilibrium may become possible if high-resolution spectroscopic observations are carried out for different airmasses, in different seasons, for different places, and if variations are monitored year by year. The astronomical spectroscopic technique involves mainly the investigation of the absorption features in high-resolution stellar spectra, but we are also considering whether accurate measures of the atmospheric O2 abundances can be obtained from medium and low resolution stellar spectra.
By using first-principles calculation, the interaction of O2 and H2O molecules with the pristine and the defective InSe monolayers is studied. It is predicted that the single Se and In vacancies exhibit significantly enhanced chemical activity toward the adsorbates compared with the perfect InSe lattice site, and the Se vacancies have a much higher chemical activity than the In vacancies. H2O molecule should be only physisorbed on the various InSe monolayers at ambient conditions, according to the calculated energies. The doping of the various InSe monolayers is discussed by the physisorbed H2O. The vacancies show a much higher chemical activity toward O2 than H2O. Although O2 molecules are still physisorbed on the pristine InSe monolayer, they will be chemisorbed on the defective InSe monolayers. Especially, our calculated energies suggest that the surface oxidation of the 2D InSe semiconductor should be dominated by the defects that expose under-coordinated host atoms, especially In atoms. Our theoretical results can help better understanding the doping and the oxidation of the 2D InSe semiconductor under ambient conditions.
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