Planetary nebulae (PNe) represent the near endpoints of evolution for stars of initial mass $sim$1-8 $M_odot$, wherein the envelope of an asymptotic giant branch (AGB) star becomes photodissociated and ionized by high-energy radiation from a newly emerging white dwarf that was the progenitor stars core. It is increasingly evident that most PNe are descended from binary systems. PNe hence provide unique insight into a diverse range of astrophysical phenomena, including the influence of companion stars on the late stages of stellar evolution; stellar wind interactions and shocks; the physics and chemistry of photoionized plasmas and photon-dominated regions (PDRs); and enrichment of the ISM in the products of intermediate-mass stellar nucleosynthesis. We describe specific examples of the potential impact of the ngVLA in each of these areas.