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Register a new userFerromagnetic and Antiferromagnetic Coupling of Spin Molecular Interfaces with High Thermal Stability
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Daniele Varsano Dr.
Publication date
2018
fields
Physics
and research's language is
English
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We report an advanced organic spin-interface architecture with magnetic remanence at room temperature, constituted by metal phthalocyanine molecules magnetically coupled with Co layer(s), mediated by graphene. Fe- and Cu-phthalocyanines assembled on graphene/Co have identical structural configurations, but FePc couples antiferromagnetically with Co up to room temperature, while CuPc couples ferromagnetically with weaker coupling and thermal stability, as deduced by element-selective X-ray magnetic circular dichroic signals. The robust antiferromagnetic coupling is stabilized by a superexchange interaction, driven by the out-of-plane molecular orbitals responsible of the magnetic ground state and electronically decoupled from the underlying metal via the graphene layer, as confirmed by ab initio theoretical predictions. These archetypal spin interfaces can be prototypes to demonstrate how antiferromagnetic and/or ferromagnetic coupling can be optimized by selecting the molecular orbital symmetry.
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The structural and magnetic properties of a series of superlattices consisting of two ferromagnetic metals La$_{0.7}$Sr$_{0.3}$MnO$_3$ (LSMO) and SrRuO$_3$ (SRO) grown on (001) oriented SrTiO$_3$ are studied. Superlattices with a fixed LSMO layer thickness of 20 unit cells (u.c.) and varying SRO layer thickness show a sudden drop in magnetization on cooling through temperature where both LSMO and SRO layers are ferromagnetic. This behavior suggests an antiferromagnetic coupling between the layers. In addition, the samples having thinner SRO layers (n TEXTsymbol{<} 6) exhibit enhanced saturation magnetization at 10 K. These observations are attributed to the possible modification in the stereochemistry of the Ru and Mn ions in the interfacial region.
Transparent conducting oxides (TCOs) and transparent oxide semiconductors (TOSs) have become necessary materials for a variety of applications in the information and energy technologies, ranging from transparent electrodes to active electronics components. Perovskite barium stannate (BaSnO3), a new TCO or TOS system, is a potential platform for realizing optoelectronic devices and observing novel electronic quantum states due to its high electron mobility, excellent thermal stability, high transparency, structural versatility, and flexible doping controllability at room temperature. This article reviews recent progress in the doped BaSnO3 system, discussing the wide physical properties, electron-scattering mechanism, and demonstration of key semiconducting devices such as pn diodes and field-effect transistors. Moreover, we discuss the pathways to achieving two-dimensional electron gases at the interface between BaSnO3 and other perovskite oxides and describe remaining challenges for observing novel quantum phenomena at the heterointerface.
To develop silicon-based spintronic devices, we have explored high-quality ferromagnetic Fe$_{3}$Si/silicon (Si) structures. Using low-temperature molecular beam epitaxy at 130 $^circ$C, we realize epitaxial growth of ferromagnetic Fe$_{3}$Si layers on Si (111) with keeping an abrupt interface, and the grown Fe$_{3}$Si layer has the ordered $DO_{3}$ phase. Measurements of magnetic and electrical properties for the Fe$_{3}$Si/Si(111) yield a magnetic moment of ~ 3.16 $mu_{B}$/f.u. at room temperature and a rectifying Schottky-diode behavior with the ideality factor of ~ 1.08, respectively.
We use textit{ab-initio} calculations to investigate spin-orbit torques (SOTs) in FeRh(001) deposited on W(100). Since FeRh undergoes a ferromagnetic-antiferromagnetic phase transition close to room temperature, we consider both phases of FeRh. In the antiferromagnetic case we find that the effective magnetic field of the even torque is staggered and therefore ideal to induce magnetization dynamics or to switch the antiferromagnet (AFM). At the antiferromagnetic resonance the inverse SOT induces a current density, which can be determined from the SOT. In the ferromagnetic case our calculations predict both even and odd components of the SOT, which can also be used to describe the ac and dc currents induced at the ferromagnetic resonance. For comparison we compute the SOTs in the c($2times 2$) AFM state of Fe/W(001).
The understanding of orbital hybridization and spin-polarization at the organic-ferromagnetic interface is essential in the search for efficient hybrid spintronic devices. Here, using first-principles calculations, we report a systematic study of spin-split hybrid states of C$_{60}$ deposited on various ferromagnetic surfaces: bcc-Cr(001), bcc-Fe(001), bcc-Co(001), fcc-Co(001) and hcp-Co(0001). We show that the adsorption geometry of the molecule with respect to the surface crystallographic orientation of the magnetic substrate as well as the strength of the interaction play an intricate role in the spin-polarization of the hybrid orbitals. We find that a large spin-polarization in vacuum above the buckyball can only be achieved if the molecule is adsorbed upon a bcc-(001) surface by its pentagonal ring. Therefore bcc-Cr(001), bcc-Fe(001) and bcc-Co(001) are the optimal candidates. Spin-polarized scanning tunneling spectroscopy measurements on single C$_{60}$ adsorbed on Cr(001) and Co/Pt(111) also confirm that both the symmetry of the substrate and of the molecular conformation have a strong influence on the induced spin polarization. Our finding may give valuable insights for further engineering of spin filtering devices through single molecular orbitals.
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