This paper is devoted to the construction of differential geometric invariants for the classification of Quaternionic vector bundles. Provided that the base space is a smooth manifold of dimension two or three endowed with an involution that leaves fixed only a finite number of points, it is possible to prove that the Wess-Zumino term and the Chern-Simons invariant yield topological quantities able to distinguish between inequivalent realization of Quaternionic structures.