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Register a new userGas phase Elemental abundances in Molecular cloudS (GEMS) I. The prototypical dark cloud TMC 1
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GEMS is an IRAM 30m Large Program whose aim is determining the elemental depletions and the ionization fraction in a set of prototypical star-forming regions. This paper presents the first results from the prototypical dark cloud TMC 1. Extensive millimeter observations have been carried out with the IRAM 30m telescope (3mm and 2mm) and the 40m Yebes telescope (1.3cm and 7mm) to determine the fractional abundances of CO, HCO+, HCN, CS, SO, HCS+, and N2H+ in three cuts which intersect the dense filament at the well-known positions TMC 1-CP, TMC 1-NH3, and TMC 1-C, covering a visual extinction range from Av~3 to ~20mag. Two phases with differentiated chemistry can be distinguished: i) the translucent envelope with molecular hydrogen densities of (1-5)x10$^3$ cm$^{-3}$; and ii) the dense phase, located at Av>10mag, with molecular hydrogen densities >10$^4$ cm$^{-3}$. Observations and modeling show that the gas phase abundances of C and O progressively decrease along the C+/C/CO transition zone where C/H~8x10$^{-5}$ and C/O~0.8-1, until the beginning of the dense phase at Av~10 mag. This is consistent with the grain temperatures being below the CO evaporation temperature in this region. In the case of sulfur, a strong depletion should occur before the translucent phase where we estimate a S/H~(0.4 - 2.2) x10$^{-6}$, an abundance ~7-40 times lower than the solar value. A second strong depletion must be present during the formation of the thick icy mantles to achieve the values of S/H measured in the dense cold cores (S/H~8x10$^{-8}$). Based on our chemical modeling, we constrain the value of $zeta_{rm H_2}$ to ~(0.5 - 1.8) x10$^{-16}$ s$^{-1}$ in the translucent cloud.
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Gas phase Elemental abundances in Molecular CloudS (GEMS) is an IRAM 30m Large Program designed to estimate the S, C, N, and O depletions and gas ionization degree, X(e-), in a set of star-forming filaments of Taurus, Perseus and Orion. Our immediate goal is to build up a complete database of molecular abundances that can serve as an observational basis for estimating X(e-) and the C, O, N, and S depletions through chemical modeling. We observed and derived the abundances of 14 species (13CO, C18O, HCO+, H13CO+, HC18O+, HCN, H13CN, HNC, HCS+, CS, SO, 34SO, H2S, and OCS) in 244 positions, covering the AV 3 to 100 mag, n(H2) a few 10$^{3}$ to 10$^6$ cm$^{-3}$, and Tk 10 to 30 K ranges in these clouds, avoiding protostars, HII regions, and outflows. A statistical analysis is carried out to identify general trends between different species and with physical parameters. Relations between molecules reveal strong linear correlations which define three different families: (1) 13CO and C18O; (2) H13CO+, HC18O+, H13CN, and HNC; and (3) the S-bearing molecules. The abundances of the CO isotopologs increase with the gas kinetic temperature until TK 15 K. For higher temperatures, the abundance remains constant with a scatter of a factor of 3. The abundances of H13CO+, HC18O+, H13CN, and HNC are well correlated with each other, and all of them decrease with molecular hydrogen density, following the law n(H2)$^{-0.8pm0.2}$. The abundances of S-bearing species also decrease with n(H2) at a rate of (S-bearing/H)gas n(H2)$^{-0.6pm0.1}$. The abundances of molecules belonging to groups 2 and 3 do not present any clear trend with gas temperature. At scales of molecular clouds, the C18O abundance is the quantity that better correlates with the cloud mass. We discuss the utility of the 13CO/C18O, HCO+/H13CO+, and H13CO+/H13CN abundance ratios as chemical diagnostics of star formation in external galaxies.
CS is among the most abundant gas-phase S-bearing molecules in cold dark molecular clouds. It is easily observable with several transitions in the millimeter wavelength range, and has been widely used as a tracer of the gas density in the interstellar medium in our Galaxy and external galaxies. Chemical models fail to account for the observed CS abundances when assuming the cosmic value for the elemental abundance of sulfur. The CS+O -> CO + S reaction has been proposed as a relevant CS destruction mechanism at low temperatures, and could explain the discrepancy between models and observations. Its reaction rate has been experimentally measured at temperatures of 150-400 K, but the extrapolation to lower temperatures is doubtful. Here we calculate the CS+O reaction rate at temperatures <150 K which are prevailing in the interstellar medium. We performed ab initio calculations to obtain the three lowest PES of the CS+O system. These PESs are used to study the reaction dynamics, using several methods to eventually calculate the CS+O thermal reaction rates. We compare the results of our theoretical calculations for 150-400 K with those obtained in the laboratory. Our detailed theoretical study on the CS+O reaction, which is in agreement with the experimental data obtained at 150-400 K, demonstrates the reliability of our approach. After a careful analysis at lower temperatures, we find that the rate constant at 10 K is negligible, which is consistent with the extrapolation of experimental data using the Arrhenius expression. We use the updated chemical network to model the sulfur chemistry in TMC1 based on molecular abundances determined from GEMS project observations. In our model, we take into account the expected decrease of the cosmic ray ionization rate along the cloud. The abundance of CS is still overestimated when assuming the cosmic value for the sulfur abundance.
Sulphur is one of the most abundant elements in the Universe. Surprisingly, sulphuretted molecules are not as abundant as expected in the interstellar medium, and the identity of the main sulphur reservoir is still an open question. Our goal is to investigate the H$_{2}$S chemistry in dark clouds, as this stable molecule is a potential sulphur reservoir. Using millimeter observations of CS, SO, H$_{2}$S, and their isotopologues, we determine the physical conditions and H$_{2}$S abundances along the cores TMC 1-C, TMC 1-CP, and Barnard 1b. The gas-grain model Nautilus is then used to model the sulphur chemistry and explore the impact of photo-desorption and chemical desorption on the H$_2$S abundance. Our model shows that chemical desorption is the main source of gas-phase H$_2$S in dark cores. The measured H$_{2}$S abundance can only be fitted if we assume that the chemical desorption rate decreases by more than a factor of 10 when $n_{rm H}>2times10^{4}$. This change in the desorption rate is consistent with the formation of thick H$_2$O and CO ice mantles on grain surfaces. The observed SO and H$_2$S abundances are in good agreement with our predictions adopting an undepleted value of the sulphur abundance. However, the CS abundance is overestimated by a factor of $5-10$. Along the three cores, atomic S is predicted to be the main sulphur reservoir. We conclude that the gaseous H$_2$S abundance is well reproduced, assuming undepleted sulphur abundance and chemical desorption as the main source of H$_2$S. The behavior of the observed H$_{2}$S abundance suggests a changing desorption efficiency, which would probe the snowline in these cores. Our model, however, overestimates the observed gas-phase CS abundance. Given the uncertainty in the sulphur chemistry, our data are consistent with a cosmic elemental S abundance with an uncertainty of a factor of 10.
We study Giant Molecular Cloud (GMC) environments surrounding 10 Infrared Dark Clouds (IRDCs), using $^{13}$CO(1-0) emission from the Galactic Ring Survey. We measure physical properties of these IRDCs/GMCs on a range of scales extending to radii, R, of 30 pc. By comparing different methods for defining cloud boundaries and for deriving mass surface densities and velocity dispersions, we settle on a preferred CE,$tau$,G method of Connected Extraction in position-velocity space plus Gaussian fitting to opacity-corrected line profiles for velocity dispersion and mass estimation. We examine how cloud definition affects measurements of the magnitude and direction of line-of-sight velocity gradients and velocity dispersions, including associated dependencies on size scale. CE,$tau$,G-defined GMCs show velocity dispersion versus size relations $sigmapropto{s}^{1/2}$, which are consistent with the large-scale gradients being caused by turbulence. However, IRDCs have velocity dispersions that are moderately enhanced above those predicted by this scaling relation. We examine the dynamical state of the clouds finding mean virial parameters $bar{alpha}_{rm{vir}}simeq 1.0$ for GMCs and 1.6 for IRDCs, broadly consistent with models of magnetized virialized pressure-confined polytropic clouds, but potentially indicating that IRDCs have more disturbed kinematics. CE,$tau$,G-defined clouds exhibit a tight correlation of $sigma/R^{1/2}proptoSigma^n$, with $nsimeq0.7$ for GMCs and 1.3 for IRDCs (c.f., a value of 0.5 expected for a population of virialized clouds). We conclude that while GMCs show evidence for virialization over a range of scales, IRDCs may be moderately super virial. Alternatively, IRDCs could be virialized but have systematically different $^{13}$CO gas phase abundances, i.e., due to freeze-out, affecting mass estimations.
The mass of molecular gas in an interstellar cloud is often measured using line emission from low rotational levels of CO, which are sensitive to the CO mass, and then scaling to the assumed molecular hydrogen H_2 mass. However, a significant H_2 mass may lie outside the CO region, in the outer regions of the molecular cloud where the gas phase carbon resides in C or C+. Here, H_2 self-shields or is shielded by dust from UV photodissociation, where as CO is photodissociated. This H_2 gas is dark in molecular transitions because of the absence of CO and other trace molecules, and because H_2 emits so weakly at temperatures 10 K < T < 100 K typical of this molecular component. This component has been indirectly observed through other tracers of mass such as gamma rays produced in cosmic ray collisions with the gas and far-infrared/submillimeter wavelength dust continuum radiation. In this paper we theoretically model this dark mass and find that the fraction of the molecular mass in this dark component is remarkably constant (~ 0.3 for average visual extinction through the cloud with mean A_V ~ 8) and insensitive to the incident ultraviolet radiation field strength, the internal density distribution, and the mass of the molecular cloud as long as mean A_V, or equivalently, the product of the average hydrogen nucleus column and the metallicity through the cloud, is constant. We also find that the dark mass fraction increases with decreasing mean A_V, since relatively more molecular H_2 material lies outside the CO region in this case.
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