In this chapter the focus is on the properties of post-Asymptotic Giant Branch (post-AGB) stars in binary systems. Their Spectral Energy Distributions (SEDs) are very characteristic: they show a near-infrared excess, indicative of the presence of warm dust, while the central stars are too hot to be in a dust-production evolutionary phase. This allows for an efficient detection of binary post-AGB candidates. It is now well established that the near-infrared excess is produced by the inner rim of a stable dusty disc that surrounds the binary system. These discs are scaled-