Heterostructures of PbTiO$_3$/SrTiO$_3$ superlattices have shown the formation of polar vortices, in which a continuous rotation of ferroelectric polarization spontaneously forms. Recently, Shafer {it{et al.}} [Proc. Natl. Acad. Sci. (PNAS) {bf{115}}, 915 (2018)] reported strong {it{non-magnetic}} circular dichroism (CD) in resonant soft x-ray diffraction at the Ti $L_3$ edge from such superlattices. The authors ascribe the CD to the chiral rotation of a polar vector. However, a polar vector is invisible to the parity-even electric-dipole transition which governs absorption in the soft x-ray region. A realistic, non-magnetic explanation of the observed effect is found in Templeton-Templeton scattering. Following this route, the origin of the CD in Bragg diffraction is shown by us to be the chiral array of charge quadrupole moments that forms in these heterostructures. While there is no charge quadrupole moment in the spherically symmetric $3d^0$ valence state of Ti$^{4+}$, the excited state $2p_{3/2}3d(t_{2g})$ at the Ti $L_3$ resonance is known to have a quadrupole moment. Our expressions for intensities of satellite Bragg spots in resonance-enhanced diffraction of circularly polarized x-rays, including their harmonic content, account for all observations reported by Shafer {it{et al.}} We predict both intensities of Bragg spots for the second harmonic of a chiral superlattice and circular polarization created from unpolarized x-rays, in order that our successful explanation of existing diffraction data can be further scrutinized through renewed experimental investigations. The increased understanding of chiral dipole arrangements could open the door to switchable optical polarization.
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