We present a novel suite of cosmological N-body simulations called the DUSTGRAIN-pathfinder, implementing simultaneously the effects of an extension to General Relativity in the form of $f(R)$ gravity and of a non-negligible fraction of massive neutrinos. We describe the generation of simulated weak lensing and cluster counts observables within a past light-cone extracted from these simulations. The simulations have been performed by means of a combination of the MG-GADGET code and a particle-based implementation of massive neutrinos, while the light-cones have been generated using the MapSim pipeline allowing us to compute weak lensing maps through a ray-tracing algorithm for different values of the source plane redshift. The mock observables extracted from our simulations will be employed for a series of papers focussed on understanding and possibly breaking the well-known observational degeneracy between $f(R)$ gravity and massive neutrinos, i.e. the fact that some specific combinations of the characteristic parameters for these two phenomena (the $f_{R0}$ scalar amplitude and the total neutrino mass $Sigma m_{ u}$) may result indistinguishable from the standard $mathrm{Lambda CDM}$ cosmology through several standard observational probes. In particular, in the present work we show how a tomographic approach to weak lensing statistics could allow - especially for the next generation of wide-field surveys - to disentangle some of the models that appear statistically indistinguishable through standard single-redshift weak lensing probe.