In this paper, we explore quantum interference in molecular conductance from the point of view of graph theory and walks on lattices. By virtue of the Cayley-Hamilton theorem for characteristic polynomials and the Coulson-Rushbrooke pairing theorem for alternant hydrocarbons, it is possible to derive a finite series expansion of the Greens function for electron transmission in terms of the odd powers of the vertex adjacency matrix or H{u}ckel matrix. This means that only odd-length walks on a molecular graph contribute to the conductivity through a molecule. Thus, if there are only even-length walks between two atoms, quantum interference is expected to occur in the electron transport between them. However, even if there are only odd-length walks between two atoms, a situation may come about where the contributions to the QI of some odd-length walks are canceled by others, leading to another class of quantum interference. For non-alternant hydrocarbons, the finite Greens function expansion may include both even and odd powers. Nevertheless, QI can in some circumstances come about for non-alternants, from the cancellation of odd and even-length walk terms. We report some progress, but not a complete resolution of the problem of understanding the coefficients in the expansion of the Greens function in a power series of the adjacency matrix, these coefficients being behind the cancellations that we have mentioned. And we introduce a perturbation theory for transmission as well as some potentially useful infinite power series expansions of the Greens function.
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