No Arabic abstract
Local electronic effects in the vicinity of an impurity provide pivotal insight into the origin of unconventional superconductivity, especially when the materials are located on the edge of magnetic instability. In high-temperature cuprate superconductors, a strong suppression of superconductivity and appearance of low-energy bound states are clearly observed near nonmagnetic impurities. However, whether these features are common to other strongly correlated superconductors has not been established experimentally. Here, we report the {$in$} {$situ$} scanning tunneling microscopy observation of electronic structure around a nonmagnetic Zn impurity in heavy-fermion CeCo(In$_{1-x}$Zn$_x$)$_5$ films, which are epitaxially grown by the state-of-the-art molecular beam epitaxy technique. The films have very wide atomically flat terraces and Zn atoms residing on two different In sites are clearly resolved. Remarkably, no discernible change is observed for the superconducting gap at and around the Zn atoms. Moreover, the local density of states around Zn atoms shows little change inside the $c$-$f$ hybridization gap, which is consistent with calculations for a periodic Anderson model without local magnetic order. These results indicate that no nonsuperconducting region is induced around a Zn impurity and do not support the scenario of antiferromagnetic droplet formation suggested by indirect measurements in Cd-doped CeCoIn$_5$. These results also highlight a significant difference of the impurity effect between cuprates and CeCoIn$_5$, in both of which $d$-wave superconductivity arises from the non-Fermi liquid normal state near antiferromagnetic instabilities.
Quantum criticality in the normal and superconducting state of the heavy-fermion metal CeCoIn$_5$ is studied by measurements of the magnetic Gr{u}neisen ratio, $Gamma_H$, and specific heat in different field orientations and temperatures down to 50 mK. Universal temperature over magnetic field scaling of $Gamma_H$ in the normal state indicates a hidden quantum critical point at zero field. Within the superconducting state the quasiparticle entropy at constant temperature increases upon reducing the field towards zero, providing additional evidence for zero-field quantum criticality.
We investigated the effect of electron and hole doping on the high-field low-temperature superconducting state in CeCoIn$_5$ by measuring specific heat of CeCo(In$_{rm 1-x}$M$_{rm x}$)$_5$ with M=Sn, Cd and Hg and $x$ up to 0.33% at temperatures down to 0.1,K and fields up to 14,T. Although both Cd- and Hg-doping (hole-doping) suppresses the zero-field $T_c$ monotonically, $H_{c2}$ increases with small amounts of doping and has a maximum around $x$=0.2% (M=Cd). On the other hand, with Sn-doping (electron-doping) both zero-field $T_c$ and $H_{c2}$ decrease monotonically. The critical temperature for the high-field low-temperature superconducting state (so called {it Q}-state) correlates with $H_{c2}$ and $T_c$, which we interpret in support of the superconducting origin of this state.
The Ce compounds CeCoIn$_5$ and CeRhIn$_5$ are ideal model systems to study the competition of antiferromagnetism (AF) and superconductivity (SC). Here we discuss the pressure--temperature and magnetic field phase diagrams of both compounds. In CeRhIn$_5$ the interesting observation is that in zero magnetic field a coexistence AF+SC phase exist inside the AF phase below the critical pressure $p_{rm c}^star approx 2$ GPa. Above $p_{rm c}^star$ AF is suppressed in zero field but can be re-induced by applying a magnetic field. The collapse of AF under pressure coincides with the abrupt change of the Fermi surface. In CeCoIn$_5$ a new phase appears at low temperatures and high magnetic field (LTHF) which vanishes at the upper critical field $H_{rm c2}$. In both compounds the paramagnetic pair breaking effect dominates at low temperature. We discuss the evolution of the upper critical field under high pressure of both compounds and propose a simple picture of the glue of reentrant magnetism to the upper critical field in order to explain the interplay of antiferromagnetic order and superconductivity.
We present nuclear magnetic resonance (NMR) measurements on the three distinct In sites of CeCoIn$_5$ with magnetic field applied in the [100] direction. We identify the microscopic nature of the long range magnetic order (LRO) stabilized at low temperatures in fields above 10.2 T while still in the superconducting (SC) state. We infer that the ordered moment is oriented along the $hat c$-axis and map its field evolution. The study of the field dependence of the NMR shift for the different In sites indicates that the LRO likely coexists with a modulated SC phase, possibly that predicted by Fulde, Ferrell, Larkin, and Ovchinnikov. Furthermore, we discern a field region dominated by strong spin fluctuations where static LRO is absent and propose a revised phase diagram.
The heavy-fermion superconductor CeCoIn$_5$ displays an additional transition within its superconducting (SC) state, whose nature is characterized by high-precision studies of the isothermal field dependence of the entropy, derived from combined specific heat and magnetocaloric effect measurements at temperatures $Tgeq 100$ mK and fields $Hleq 12$ T aligned parallel, perpendicular and $18^circ$ off the tetragonal [100] direction. For any of these conditions, we do not observe an additional entropy contribution upon tuning at constant temperature by magnetic field from the homogeneous SC into the presumed Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) SC state. By contrast, for $Hparallel [100]$ a negative isothermal entropy contribution, compatible with spin-density-wave (SDW) ordering, is found. Our data exclude the formation of a FFLO state in CeCoIn$_5$ for out-of-plane field directions, where no SDW order exists.