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Register a new userHigh pressure effects on non-fluorinated BiS2-based superconductors La$_{1-x}$M$_x$OBiS$_2$ (M = Ti and Th)
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Layered textit{Ln}OBiS$_2$ compounds with textit{Ln} = La, Ce, Pr, Nd, and Yb can be rendered conducting and superconducting via two routes, substitution of F for O or the tetravalent ions Ti, Zr, Hf, and Th for trivalent textit{Ln} ions. Electrical resistivity measurements on non-fluorinated La$_{0.80}$Ti$_{0.20}$OBiS$_2$ and La$_{0.85}$Th$_{0.15}$OBiS$_2$ superconductors were performed between $sim$1.5 K and 300 K and under pressure up to 2.4 GPa. For both compounds, the superconducting transition temperature $T_c$, which is $sim$2.9 K at ambient pressure, gradually increases with pressure to 3.2-3.7 K at $sim$1 GPa, above which it is suppressed and the superconducting transitions become very broad. Measurements of the normal state electrical resistivity of the two compounds reveal discontinuous changes of the resistivity as a function of pressure at $sim$0.6 GPa. Surprisingly, above 1.3 GPa, semiconducting-like behavior reappears in La$_{0.80}$Ti$_{0.20}$OBiS$_2$. This study reveals a new high-pressure phase of La$_{1-x}$$M$$_x$OBiS$_2$ containing the tetravalent ions $M$ = Ti, Th which does not favor superconductivity. In contrast, application of pressure to fluorinated LaO$_0.5$F$_0.5$BiS$_2$ produces an abrupt tetragonal-monoclinic transition to a metallic phase with an enhanced $T_c$. These results demonstrate that the response of the normal and superconducting properties of LaOBiS$_2$-based compounds depends strongly on the atomic site where the electron donor ions are substituted.
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We report the electrical resistivity measurements under pressure for the recently discovered BiS2-based layered superconductors Bi4O4S3 and La(O,F)BiS2. In Bi4O4S3, the transition temperature Tc decreases monotonically without a distinct change in the metallic behavior in the normal state. In La(O,F)BiS2, on the other hand, Tc initially increases with increasing pressure and then decreases above ? 1 GPa. The semiconducting behavior in the normal state is suppressed markedly and monotonically, whereas the evolution of Tc is nonlinear. The strong suppression of the semiconducting behavior without doping in La(O,F)BiS2 suggests that the Fermi surface is located in the vicinity of some instability. In the present study, we elucidate that the superconductivity in the BiS2 layer favors the Fermi surface at the boundary between the semiconducting and metallic behaviors.
A large number of compounds which contain BiS$_{2}$ layers exhibit enhanced superconductivity upon electron doping. Much interest and research effort has been focused on BiS$_{2}$-based compounds which provide new opportunities for exploring the nature of superconductivity. Important to the study of BiS$_{2}$-based superconductors is the relation between structure and superconductivity. By modifying either the superconducting BiS$_2$ layers or the blocking layers in these layered compounds, one can effectively tune the lattice parameters, local atomic environment, electronic structure, and other physical properties of these materials. In this article, we will review some of the recent progress on research of the effects of chemical substitution in BiS$_{2}$-based compounds, with special attention given to the compounds in the $Ln$OBiS$_{2}$ ($Ln$ = La-Nd) system. Strategies which are reported to be essential in optimizing superconductivity of these materials will also be discussed.
We report the effect of applied pressures on magnetic and superconducting order in single crystals of the aliovalent La-doped iron pnictide material Ca$_{1-x}$La$_{x}$Fe$_{2}$As$_{2}$. Using electrical transport, elastic neutron scattering and resonant tunnel diode oscillator measurements on samples under both quasi-hydrostatic and hydrostatic pressure conditions, we report a series of phase diagrams spanning the range of substitution concentrations for both antiferromagnetic and superconducting ground states that include pressure-tuning through the antiferromagnetic (AFM) quantum critical point. Our results indicate that the observed superconducting phase with maximum transition temperature of $T_{c}$=47 K is intrinsic to these materials, appearing only upon suppression of magnetic order by pressure tuning through the AFM critical point. In contrast to all other intermetallic iron-pnictide superconductors with the ThCr$_2$Si$_2$ structure, this superconducting phase appears to exist only exclusively from the antiferromagnetic phase in a manner similar to the oxygen- and fluorine-based iron-pnictide superconductors with the highest transition temperatures reported to date. The unusual dichotomy between lower-$T_{c}$ systems with coexistent superconductivity and magnetism and the tendency for the highest-$T_{c}$ systems to show non-coexistence provides an important insight into the distinct transition temperature limits in different members of the iron-based superconductor family.
Local lattice structures of La$_{1.85}$Sr$_{0.15}$Cu$_{1-x}$M$_x$O$_4$ (M=Mn, Ni, and Co) single crystals are investigated by polarized extended x-ray absorption fine structure (EXAFS). The local lattice instability at low temperature is described by in-plane Cu-O bond splitting. We find that substitution of Mn for Cu causes little perturbation of local lattice instability while Ni and Co substitution strongly suppresses the instability. The suppression of superconductivity by Cu-site substitution is related to the perturbation of lattice instability, indicating that local lattice instability (polaron) plays an important role in superconductivity.
We present an investigation of the influence of structural distortions in charge-carrier doped lmco by substituting La$^{3+}$ with alkaline earth metals of strongly different ionic sizes, that is M = Ca$^{2+}$, Sr$^{2+}$, and Ba$^{2+}$, respectively. We find that both, the magnetic properties and the resistivity change non-monotonously as a function of the ionic size of M. Doping lmco with M = Sr$^{2+}$ yields higher transition temperatures to the ferromagnetically ordered states and lower resistivities than doping with either Ca$^{2+}$ or Ba$^{2+}$ having a smaller or larger ionic size than Sr$^{2+}$, respectively. From this observation we conclude that the different transition temperatures and resistivities of lmco for different M (of the same concentration $x$) do not only depend on the varying chemical pressures. The local disorder due to the different ionic sizes of La$^{3+}$ and M$^{2+}$ play an important role, too.
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