Multi-band phase variations in principle allow us to infer the longitudinal temperature distributions of planets as a function of height in their atmospheres. For example, 3.6 micron emission originates from deeper layers of the atmosphere than 4.5 micron due to greater water vapor absorption at the longer wavelength. Since heat transport efficiency increases with pressure, we expect thermal phase curves at 3.6 micron to exhibit smaller amplitudes and greater phase offsets than at 4.5 micron; this trend is not observed. Of the seven hot Jupiters with full-orbit phase curves at 3.6 and 4.5 micron, all have greater phase amplitude at 3.6 micron than at 4.5 micron, while four of seven exhibit a greater phase offset at 3.6 micron. We use a 3D radiative-hydrodynamic model to calculate theoretical phase curves of HD 189733b, assuming thermo-chemical equilibrium. The model exhibits temperature, pressure, and wavelength dependent opacity, primarily driven by carbon chemistry: CO is energetically favored on the dayside, while CH4 is favored on the cooler nightside. Infrared opacity therefore changes by orders of magnitude between day and night, producing dramatic vertical shifts in the wavelength-specific photospheres, which would complicate eclipse or phase mapping with spectral data. The model predicts greater relative phase amplitude and greater phase offset at 3.6 micron than at 4.5 micron, in agreement with the data. Our model qualitatively explains the observed phase curves, but is in tension with current thermo-chemical kinetics models that predict zonally uniform atmospheric composition due to transport of CO from the hot regions of the atmosphere.
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