Creating high-quality vector vortex (VV) beams is possible with a myriad of techniques at low power, and while a few studies have produced such beams at high-power, none have considered the impact of amplification on the vector purity. Here we employ novel tools to study the amplification of VV beams, and in particular the purity of such modes. We outline a general toolbox for such investigations and demonstrate its use in the general case of VV beams through a birefringent gain medium. Intriguingly, we show that it is possible to enhance the purity of such beams during amplification, paving the way for high-brightness VV beams, a requirement for their use in high-power applications such as laser materials processing.