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Register a new userProton-electron mass ratio from HD$^+$ revisited
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We present a new derivation of the proton-electron mass ratio from the hydrogen molecular ion, HD$^+$. The derivation entails the adjustment of the mass ratio in highly precise theory so as to reproduce accurately measured ro-vibrational frequencies. This work is motivated by recent improvements of the theory, as well as the more accurate value of the electron mass in the recently published CODATA-14 set of fundamental constants, which justifies using it as input data in the adjustment, rather than the proton mass value as done in previous works. This leads to significantly different sensitivity coefficients and, consequently, a different value and larger uncertainty margin of the proton-electron mass ratio as obtained from HD$^+$.
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Molecules with deep vibrational potential wells provide optical intervals sensitive to variation in the proton-electron mass ratio ($mu$). On one hand, polar molecules are of interest since optical state preparation techniques have been demonstrated for such species. On the other hand, it might be assumed that polar species are unfavorable candidates, because typical molecule-frame dipole moments reduce vibrational state lifetimes and cause large polarizabilities and associated Stark shifts. Here, we consider single-photon spectroscopy on a vibrational overtone transition of the polar species TeH$^+$, which is of practical interest because its diagonal Franck-Condon factors should allow rapid state preparation by optical pumping. We point out that all but the ground rotational state obtains a vanishing low-frequency scalar polarizability from coupling with adjacent rotational states, because of a fortuitous relationship between rigid rotor spacings and dipole matrix elements. We project that for good choices of spectroscopy states, demonstrated levels of field control should make possible uncertainties of order $1 times 10^{-18}$, similar to those of leading atomic ion clocks. The moderately long lived vibrational states of TeH$^+$ make possible a frequency uncertainty approaching $1 times 10^{-17}$ with one day of averaging for a single trapped ion. Observation over one year could probe for variation of $mu$ with a sensitivity approaching the $1 times 10^{-18}/textrm{yr}$ level.
Astrophysical molecular spectroscopy is an important means of searching for new physics through probing the variation of the proton-to-electron mass ratio, $mu$. New molecular probes could provide tighter constraints on the variation of $mu$ and better direction for theories of new physics. Here we summarise our previous paper citep{19SyMoCu.CN} for astronomers, highlighting the importance of accurate estimates of peak molecular abundance and temperature as well as spectral resolution and sensitivity of telescopes in different regions of the electromagnetic spectrum. Whilst none of the 11 astrophysical diatomic molecules we investigated showed enhanced sensitive rovibronic transitions at observable intensities for astrophysical environments, we have gained a better understanding of the factors that contribute to high sensitivities. From our results, CN, CP, SiN and SiC have shown the most promise of all astrophysical diatomic molecules for further investigation, with further work currently being done on CN.
We report Karl G. Jansky Very Large Array (VLA) absorption spectroscopy in four methanol (CH$_3$OH) lines in the $z = 0.88582$ gravitational lens towards PKS1830-211. Three of the four lines have very different sensitivity coefficients $K_mu$ to changes in the proton-electron mass ratio $mu$; a comparison between the line redshifts thus allows us to test for temporal evolution in $mu$. We obtain a stringent statistical constraint on changes in $mu$ by comparing the redshifted 12.179 GHz and 60.531 GHz lines, $[Delta mu/mu] leq 1.1 times 10^{-7}$ ($2sigma$) over $0 < z leq 0.88582$, a factor of $approx 2.5$ more sensitive than the best earlier results. However, the higher signal-to-noise ratio (by a factor of $approx 2$) of the VLA spectrum in the 12.179 GHz transition also indicates that this line has a different shape from that of the other three CH$_3$OH lines (at $> 4sigma$ significance). The sensitivity of the above result, and that of all earlier CH$_3$OH studies, is thus likely to be limited by unknown systematic errors, probably arising due to the frequency-dependent structure of PKS1830-211. A robust result is obtained by combining the three lines at similar frequencies, 48.372, 48.377 and 60.531 GHz, whose line profiles are found to be in good agreement. This yields the $2sigma$ constraint $[Delta mu/mu] lesssim 4 times 10^{-7}$, the most stringent current constraint on changes in $mu$. We thus find no evidence for changes in the proton-electron mass ratio over a lookback time of $approx 7.5$ Gyrs.
Astrophysical molecular spectroscopy is an important method of searching for new physics through probing the variation of the proton-to-electron mass ratio, $mu$, with existing constraints limiting variation to a fractional change of less than 10$^{-17}$/year. To improve on this constraint and therefore provide better guidance to theories of new physics, new molecular probes will be useful. These probes must have spectral transitions that are observable astrophysically and have different sensitivities to variation in the proton-to-electron mass ratio. Here, we concisely detail how astrophysical observations constrain the set of potential molecular probes and promising sensitive transitions based on how the frequency and intensity of these transitions align with available telescopes and observational constraints. Our detailed investigation focuses on rovibronic transitions in astrophysical diatomic molecules, using the spectroscopic models of 11 diatomics to identify sensitive transitions and probe how they generally arise in real complex molecules with many electronic states and fine structure. While none of the 11 diatomics investigated have sensitive transitions likely to be astrophysically observable, we have found that at high temperatures (1000 K) five of these diatomics have a significant number of low intensity sensitive transitions arising from an accidental near-degeneracy between vibrational levels in the ground and excited electronic state. This insight enables screening of all astrophysical diatomics as potential probes of proton-to-electron mass variation, with CN, CP, SiN and SiC being the most promising candidates for further investigation for sensitivity in rovibronic transitions.
Molecular transitions recently discovered at redshift z_abs=2.059 toward the bright background quasar J2123-0050 are analysed to limit cosmological variation in the proton-to-electron mass ratio, mu=m_p/m_e. Observed with the Keck telescope, the optical spectrum has the highest resolving power and largest number (86) of H_2 transitions in such analyses so far. Also, (7) HD transitions are used for the first time to constrain mu-variation. These factors, and an analysis employing the fewest possible free parameters, strongly constrain mus relative deviation from the current laboratory value: dmu/mu =(+5.6+/-5.5_stat+/-2.7_sys)x10^{-6}. This is the first Keck result to complement recent constraints from three systems at z_abs>2.5 observed with the Very Large Telescope.
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