On a compact $n$-dimensional manifold $M$, it is well known that a critical metric of the total scalar curvature, restricted to the space of metrics with unit volume, is Einstein. It has been conjectured that a critical metric of the total scalar curvature, restricted to the space of metrics with constant scalar curvature of unit volume, will also be Einstein. It was shown that this conjecture is true when $M$ together with a critical metric has harmonic curvature or the metric is Bach flat. In this paper, we tried to prove this conjecture with a divergence-free Bach tensor.