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Register a new userMolecular-Cloud-Scale Chemical Composition II: Mapping Spectral Line Survey toward W3(OH) in the 3 mm Band
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In order to study a molecular-cloud-scale chemical composition, we have conducted a mapping spectral line survey toward the Galactic molecular cloud W3(OH), which is one of the most active star forming regions in the Perseus arm, with the NRO 45 m telescope. We have observed the area of 16 $times$ 16, which corresponds to 9.0 pc $times$ 9.0 pc. The observed frequency ranges are 87--91, 96--103, and 108--112 GHz. We have prepared the spectrum averaged over the observed area, in which 8 molecular species CCH, HCN, HCO$^+$, HNC, CS, SO, C$^{18}$O, and $^{13}$CO are identified. On the other hand, the spectrum of the W3(OH) hot core observed at a 0.17 pc resolution shows the lines of various molecules such as OCS, H$_2$CS CH$_3$CCH, and CH$_3$CN, in addition to the above species. In the spatially averaged spectrum, emission of the species concentrated just around the star-forming core such as CH$_3$OH and HC$_3$N is fainter than in the hot core spectrum, whereas emission of the species widely extended over the cloud such as CCH is relatively brighter. We have classified the observed area into 5 subregions according to the integrated intensity of $^{13}$CO, and have evaluated the contribution to the averaged spectrum from each subregion. The CCH, HCN, HCO$^+$, and CS lines can be seen even in the spectrum of the subregion with the lowest $^{13}$CO integrated intensity range ($< 10$ K km s$^{-1}$). Thus, the contributions of the spatially extended emission is confirmed to be dominant in the spatially averaged spectrum.
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We have conducted a mapping spectral line survey toward the Galactic giant molecular cloud W51 in the 3 mm band with the Mopra 22 m telescope in order to study an averaged chemical composition of the gas extended over a molecular cloud scale in our Galaxy. We have observed the area of $25 times 30$, which corresponds to 39 pc $times$ 47 pc. The frequency ranges of the observation are 85.1 - 101.1 GHz and 107.0 - 114.9 GHz. In the spectrum spatially averaged over the observed area, spectral lines of 12 molecular species and 4 additional isotopologues are identified. An intensity pattern of the spatially-averaged spectrum is found to be similar to that of the spiral arm in the external galaxy M51, indicating that these two sources have similar chemical compositions. The observed area has been classified into 5 sub-regions according to the integrated intensity of $^{13}$CO($J=1-0$) ($I_{rm ^{13}CO}$), and contributions of the fluxes of 11 molecular lines from each sub-region to the averaged spectrum have been evaluated. For most of molecular species, 50 % or more of the flux come from the sub-regions with $I_{rm ^{13}CO}$ from 25 K km s$^{-1}$ to 100 K km s$^{-1}$, which does not involve active star forming regions. Therefore, the molecular-cloud-scale spectrum observed in the 3 mm band hardly represents the chemical composition of star forming cores, but mainly represents the chemical composition of an extended quiescent molecular gas. The present result constitutes a sound base for interpreting the spectra of external galaxies at a resolution of a molecular cloud scale ($sim10$ pc) or larger.
Spectral line survey observations are conducted toward the high-mass protostar candidate NGC 2264 CMM3 in the 4 mm, 3 mm, and 0.8 mm bands with the Nobeyama 45 m telescope and the Atacama Submillimeter Telescope Experiment (ASTE) 10 m telescope. In total, 265 emission lines are detected in the 4 mm and 3 mm bands, and 74 emission lines in the 0.8 mm band. As a result, 36 molecular species and 30 isotopologues are identified. In addition to the fundamental molecular species, many emission lines of carbon-chain molecules such as HC5N, C4H, CCS, and C3S are detected in the 4 mm and 3 mm bands. Deuterated molecular species are also detected with relatively strong intensities. On the other hand, emission lines of complex organic molecules such as HCOOCH3, and CH3OCH3 are found to be weak. For the molecules for which multiple transitions are detected, rotation temperatures are derived to be 7-33 K except for CH3OH. Emission lines with high upper-state energies (Eu > 150 K) are detected for CH3OH, indicating existence of a hot core. In comparison with the chemical composition of the Orion KL, carbon-chain molecules and deuterated molecules are found to be abundant in NGC 2264 CMM3, while sulfur-bearing species and complex organic molecules are deficient. These characteristics indicate chemical youth of NGC 2264 CMM3 in spite of its location at the center of the cluster forming core, NGC 2264 C.
We have conducted a spectral line survey observation in the 3 mm band toward the low-metallicity dwarf galaxy IC10 with the 45 m radio telescope of Nobeyama Radio Observatory to explore its chemical composition at a molecular-cloud scale (~80 pc). The CS, SO, CCH, HCN, HCO+, and HNC lines are detected for the first time in this galaxy in addition to the CO and 13CO lines, while c-C3H2, CH3OH, CN, C18O, and N2H+ lines are not detected. The spectral intensity pattern is found to be similar to those observed toward molecular clouds in the Large Magellanic Cloud, whose metallicity is as low as IC10. Nitrogen-bearing species are deficient in comparison with the Galactic molecular clouds due to a lower elemental abundance of nitrogen. CCH is abundant in comparison with Galactic translucent clouds, whereas CH3OH may be deficient. These characteristic trends for CCH and CH3OH are also seen in the LMC, and seem to originate from photodissociation regions more extended in peripheries of molecular clouds due to the lower metallicity condition.
Spectral line survey observations of 7 molecular clouds in the Large Magellanic Cloud (LMC) have been conducted in the 3 mm band with the Mopra 22 m telescope to reveal chemical compositions in low metallicity conditions. Spectral lines of fundamental species such as CS, SO, CCH, HCN, HCO+, and HNC are detected in addition to those of CO and 13CO, while CH3OH is not detected in any source and N2H+ is marginally detected in two sources. The molecular-cloud scale (10 pc scale) chemical composition is found to be similar among the 7 sources regardless of different star formation activities, and hence, it represents the chemical composition characteristic to the LMC without influences of star formation activities. In comparison with chemical compositions of Galactic sources, the characteristic features are (1) deficient N-bearing molecules, (2) abundant CCH, and (3) deficient CH3OH. The feature (1) is due to a lower elemental abundance of nitrogen in the LMC, whereas the features (2) and (3) seem to originate from extended photodissociation regions and warmer temperature in cloud peripheries due to a lower abundance of dust grains in the low metallicity condition. In spite of general resemblance of chemical abundances among the seven sources, the CS/HCO+ and SO/HCO+ ratios are found to be slightly higher in a quiescent molecular cloud. An origin of this trend is discussed in relation to possible depletion of sulfur along molecular cloud formation.
We have conducted a spectral line survey in the 3 mm and 2 mm bands toward two positions in a spiral arm of M51 (NGC 5194) with the IRAM 30 m telescope. In this survey, we have identified 13 molecular species, including CN, CCH, N2H+, HNCO, and CH3OH. Furthermore, 6 isotopologues of the major species have been detected. On the other hand, SiO, HC3N, CH3CN, and the deuterated species such as DCN and DCO+ are not detected. The deuterium fractionation ratios are evaluated to be less than 0.8 % and 1.2 % for DCN/HCN and DCO+/HCO+, respectively. By comparing the results of the two positions with different star formation activities, we have found that the observed chemical compositions do not strongly depend on star formation activities. They seem to reflect a chemical composition averaged over the 1-kpc scale region including many giant molecular clouds. Among the detected molecules CN, CCH, and CH3OH are found to be abundant. High abundances of CN, and CCH are consistent with the above picture of a wide spread distribution of molecules, because they can be produced by photodissociation. On the other hand, it seems likely that CH3OH is liberated into the gas phase by shocks associated with large scale phenomena such as cloud-cloud collisions and/or by non-thermal desorption processes such as photoevaporation due to cosmic-ray induced UV photons. The present result demonstrates a characteristic chemical composition of a giant molecular cloud complex in the spiral arm, which can be used as a standard reference for studying chemistry in AGNs and starbursts.
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