The present work reported a conclusive evidence for anti-magnetic rotational (AMR) band in an odd-odd nucleus 142Eu. Parity of the states of a quadrupole sequence in 142Eu was firmly identified from polarization measurements using the Indian National Gamma Array and lifetimes of some of the states in the same structure were measured using the Doppler shift attenuation method. The decreasing trends of the deduced quadrupole transition strength B(E2) with spin, along with increasing J(2) / B(E2) values conclusively established the origin of these states as arising from Antimagnetic rotation. The results were well reproduced by numerical calculations within the framework of a semi-classical geometric model.