We study the generation of biphoton modally entangled states in such waveguide structures that lead to spectrum broadening. The process of spontaneous parametric down conversion (SPDC) has been considered for the biphoton generation. The main subject of our study is the dependence of the biphoton spectra on the structure spatial characteristics. The representation of the core structures as definite assembles of nonlinear layers allows us to find analytical description for biphoton spectrum. We show that chirped biphotons with discrete as well as continuous spectra can be generated depending on the waveguide structure. The conditions for spectrum discretization are obtained analytically. It is shown that the biphoton entangled states can be controlled by varying the parameters of the waveguide structure.