No Arabic abstract
Remarkably persistent mixing and non-mixing regions (islands) are observed to coexist in a three-dimensional dynamical system where randomness is expected. The track of an x-ray opaque particle in a spherical shell half-filled with dry non-cohesive particles and periodically rotated about two axes reveals interspersed structures that are spatially complex and vary non-trivially with the rotation angles. The geometric skeleton of the structures forms from the subtle interplay between fluid-like mixing by stretching-and-folding, and solids mixing by cutting-and-shuffling, which is described by the mathematics of piecewise isometries. In the physical system, larger islands predicted by the cutting-and-shuffling model alone can persist despite the presence of stretching-and-folding flows and particle-collision-driven diffusion, while predicted smaller islands are not observed. By uncovering the synergy of simultaneous fluid and solid mixing, we point the way to a more fundamental understanding of advection driven mixing in materials with both solid and flowing regions.
Phase behavior of large three-dimensional complex plasma systems under microgravity conditions onboard the International Space Station is investigated. The neutral gas pressure is used as a control parameter to trigger phase changes. Detailed analysis of structural properties and evaluation of three different melting/freezing indicators reveal that complex plasmas can exhibit melting by increasing the gas pressure. Theoretical estimates of complex plasma parameters allow us to identify main factors responsible for the observed behavior. The location of phase states of the investigated systems on a relevant equilibrium phase diagram is estimated. Important differences between the melting process of 3D complex plasmas under microgravity conditions and that of flat 2D complex plasma crystals in ground based experiments are discussed.
Solid-solid collapse transition in open framework structures is ubiquitous in nature. The real difficulty in understanding detailed microscopic aspects of such transitions in molecular systems arises from the interplay between different energy and length scales involved in molecular systems, often mediated through a solvent. In this work we employ Monte Carlo (MC) simulations to study the collapse transition in a model molecular system interacting via both isotropic as well as anisotropic interactions having different length and energy scales. The model we use is known as Mercedes-Benz (MB) which for a specific set of parameters sustains three solid phases: honeycomb, oblique and triangular. In order to study the temperature induced collapse transition, we start with a metastable honeycomb solid and induce transition by heating. High density oblique solid so formed has two characteristic length scales corresponding to isotropic and anisotropic parts of interaction potential. Contrary to the common believe and classical nucleation theory, interestingly, we find linear strip-like nucleating clusters having significantly different order and average coordination number than the bulk stable phase. In the early stage of growth, the cluster grows as linear strip followed by branched and ring-like strips. The geometry of growing cluster is a consequence of the delicate balance between two types of interactions which enables the dominance of stabilizing energy over the destabilizing surface energy. The nuclei of stable oblique phase are wetted by intermediate order particles which minimizes the surface free energy. We observe different pathways for pressure and temperature induced transitions.
We consider dense rapid shear flow of inelastically colliding hard disks. Navier-Stokes granular hydrodynamics is applied accounting for the recent finding cite{Luding,Khain} that shear viscosity diverges at a lower density than the rest of constitutive relations. New interpolation formulas for constitutive relations between dilute and dense cases are proposed and justified in molecular dynamics (MD) simulations. A linear stability analysis of the uniform shear flow is performed and the full phase diagram is presented. It is shown that when the inelasticity of particle collision becomes large enough, the uniform sheared flow gives way to a two-phase flow, where a dense solid-like striped cluster is surrounded by two fluid layers. The results of the analysis are verified in event-driven MD simulations, and a good agreement is observed.
The free energy landscape responsible for crystallization can be complex even for relatively simple systems like hard sphere and charged stabilized colloids. In this work, using hard-core repulsive Yukawa model, which is known to show complex phase behavior consisting of fluid, FCC and BCC phases, we studied the interplay between the free energy landscape and polymorph selection during crystallization. When the stability of the BCC phase with respect to the fluid phase is gradually increased by changing the temperature and pressure at a fixed fluid-FCC stability, the final phase formed by crystallization is found to undergo a switch from the FCC to the BCC phase, even though FCC remains thermodynamically the most stable phase. We further show that the nature of local bond-orientational order parameter fluctuations in the metastable fluid phase as well as the composition of the critical cluster depend delicately on the free energy landscape, and play a decisive role in the polymorph selection during crystallization.
The rheology of biological tissues is important for their function, and we would like to better understand how single cells control global tissue properties such as tissue fluidity. A confluent tissue can fluidize when cells diffuse by executing a series of cell rearrangements, or T1 transitions. In a disordered 2D vertex model, the tissue fluidizes when the T1 energy barriers disappear as the target shape index approaches a critical value ($s^*_{0} sim 3.81$), and the shear modulus describing the linear response also vanishes at this same critical point. However, the ordered ground states of 2D vertex models become linearly unstable at a lower value of the target shape index (3.72) [1,2]. We investigate whether the ground states of the 2D vertex model are fluid-like or solid-like between 3.72 and 3.81 $-$ does the equation of state for these systems have two branches, like glassy particulate matter, or only one? Using four-cell and many-cell numerical simulations, we demonstrate that for a hexagonal ground state, T1 energy barriers only vanish at $sim 3.81$, indicating that ordered systems have the same critical point as disordered systems. We also develop a simple geometric argument that correctly predicts how non-linear stabilization disappears at $s^*_{0}$ in ordered systems.