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Register a new userAtomic-scale structure analysis of a molecule at a (6-nanometer)$^3$ ice crystal
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Water is the most important solvent in nature. It is a crucial issue to study interactions among water molecules. Nuclear magnetic resonance (NMR) spectroscopy is one of the most powerful tools to detect magnetic interactions for the structure analysis of a molecule with broad applications. But conventional NMR spectroscopy requires macroscopic sample quantities with hampers in investigating nanoscale structures. Through quantum control of a single spin quantum sensor, magnetic resonance spectroscopy of nanoscale organic molecules and single molecules has been achieved. However, the measurement of the dipolar interaction of nuclear spins within a molecule at nanoscale and the analysis of its structure remain a big challenge. Here we succeed in detecting the NMR spectrum from an ice crystal with (6-nanometer)$^3$ detection volume. More importantly, the magnetic dipolar coupling between two proton nuclear spins of a water molecule was recorded. The resolved intra-molecule magnetic dipolar interactions are about 15 kHz and 33 kHz with spectral resolution at a few kHz. Analysis of the interaction-resolved NMR spectroscopy provides a spatial view of nanoscale ice crystal, from which the orientation of a water-molecule bond is derived and further the length of the bond can be got. This work enables NMR spectroscopy applications in single molecule structure analysis, provides a further tool for nanocrystalline and confined water research.
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Self-assembled semiconductor quantum dots show remarkable optical and spin coherence properties, which have lead to a concerted research effort examining their potential as a quantum bit for quantum information science1-6. Here, we present an alternative application for such devices, exploiting recent achievements of charge occupation control and the spectral tunability of the optical emission of quantum dots by electric fields7 to demonstrate high-sensitivity electric field measurement. In contrast to existing nanometer-scale electric field sensors, such as single electron transistors8-11 and mechanical resonators12,13, our approach relies on homodyning light resonantly Rayleigh scattered from a quantum dot transition with the excitation laser and phase sensitive lock-in detection. This offers both static and transient field detection ability with high bandwidth operation and near unity quantum efficiency. Our theoretical estimation of the static field sensitivity for typical parameters, 0.5 V/m/ surd Hz, compares favorably to the theoretical limit for single electron transistor-based electrometers. The sensitivity level of 5 V/m/ surd Hz we report in this work, which corresponds to 6.4 * 10-6 e/ surd Hz at a distance of 12 nm, is worse than this theoretical estimate, yet higher than any other result attained at 4.2 K or higher operation temperature.
We describe the design, fabrication, and measurement of a cavity opto-mechanical system consisting of two nanobeams of silicon nitride in the near-field of each other, forming a so-called zipper cavity. A photonic crystal patterning is applied to the nanobeams to localize optical and mechanical energy to the same cubic-micron-scale volume. The picrogram-scale mass of the structure, along with the strong per-photon optical gradient force, results in a giant optical spring effect. In addition, a novel damping regime is explored in which the small heat capacity of the zipper cavity results in blue-detuned opto-mechanical damping.
We demonstrate nanometer-scale spatial control of inter-atomic interactions in a Bose-Einstein condensate of ytterbium(Yb). A pulsed optical standing wave, tuned near an optical Feshbach resonance varies the s-wave scattering length continuously across the standing wave pattern. The modulated mean-field energy with a spatial period of every 278 nm is monitored by a diffraction pattern in a time-of-flight image. We observe a wide scattering length control of up to 160 nm. The demonstrated spatial modulation of the scattering length proves that the high resolution control of atomic interactions is possible.
I examine a variety of snow crystal growth measurements taken at a temperature of -5 C, as a function of supersaturation, background gas pressure, and crystal morphology. Both plate-like and columnar prismatic forms are observed under different conditions at this temperature, along with a diverse collection of complex dendritic structures. The observations can all be reasonably understood using a single comprehensive physical model for the basal and prism attachment kinetics, together with particle diffusion of water vapor through the surrounding medium and other well-understood physical processes. A critical model feature is structure-dependent attachment kinetics (SDAK), for which the molecular attachment kinetics on a faceted surface depend strongly on the nearby mesoscopic structure of the crystal.
Recent advances in scanning probe techniques rely on the chemical functionalization of the probe-tip termination by a single molecule. The success of this approach opens the tantalizing prospect of introducing spin sensitivity through the functionalization by a magnetic molecule. Here, we use a nickelocene-terminated tip (Nc-tip), which offers the possibility of producing spin excitations on the tip apex of a scanning tunneling microscope (STM). We show that when the Nc-tip is a hundred pm away from point contact with a surface-supported object, magnetic effects may be probed through changes in the spin excitation spectrum of nickelocene. We use this detection scheme to simultaneously determine the exchange field and the spin polarization of the sample with atomic-scale resolution. Our findings demonstrate that the Nc-tip is a powerful probe for investigating surface magnetism with STM, from single magnetic atoms to surfaces.
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