No Arabic abstract
This paper is devoted to present the results of creation of gold nanoparticles on titanium surface. We focused on the problem how to create gold nanoparticles on the titanium surface with defined particle size and distribution, which could be interesting for several applications (e.g. providing well-defined substrates for biomedical research, etc.). To do that the sample is affected by the complex physical rout of gold nanoparticles formation: by gold ion implantation, thin Au layer deposition and thermal annealing. The effect of the technology, influence on the surface structure and its parameters were investigated by the X-ray diffraction, Scanning Electron and Atomic Force Microscopy, as well as by Secondary Neutral Mass Spectrometry methods.
In this letter, we study how coupling between AuNPs and ZnO thin films affects their emission properties. The emission intensity of ZnO thin films changes when Al2O3 spacer layer of different thickness are included in ZnO/Au films, consistent with theoretical predictions. The emission properties are also controlled using the polarization of the excitation source. Emission properties depended on the polarization of the excitation source because of the surface plasmon resonance of AuNPs. The photoluminescence anisotropy of these systems shows that enhanced photoluminescence can be achieved through coupling of the emission from ZnO with the surface plasmon resonance of AuNPs.
We present theoretical calculations for the absorption properties of protein-coated gold nanoparticles on graphene and graphite substrates. As the substrate is far away from nanoparticles, numerical results show that the number of protein bovine serum molecules molecules aggregating on gold surfaces can be quantitatively determined for gold nanoparticles with arbitrary size by means of the Mie theory and the absorption spectra. The presence of graphitic substrate near protein-conjugated gold nanoparticles substantially enhances the red shift of the surface plasmon resonances of the nanoparticles. Our findings show that graphene and graphite provide the same absorption band when the distance between the nanoparticles and the substrate is large. However at shorter distances, the resonant wavelength peak of graphene-particle system differs from that of graphite-particle system. Furthermore, the influence of the chemical potential of graphene on the optical spectra is also investigated.
We report the investigation of the generation and detection of GHz coherent acoustic phonons in plasmonic gold nanoparticles superlattices (NPS). The experiments have been performed from an optical femtosecond pump-probe scheme across the optical plasmon resonance of the superlattice. Our experiments allow to estimate the collective elastic response (sound velocity) of the NPS as well as an estimate of the nano-contact elastic stiffness. It appears that the light-induced coherent acoustic phonon pulse has a typical in-depth spatial extension of about 45 nm which is roughly 4 times the optical skin depth in gold. The modeling of the transient optical reflectivity indicates that the mechanism of phonon generation is achieved through ultrafast heating of the NPS assisted by light excitation of the volume plasmon. These results demonstrate how it is possible to map the photon-electron-phonon interaction in subwavelength nanostructures.
In this work, we have developed economic process to elaborate scalable titanium dioxide nanotube layers which show a tunable functionality. The titanium dioxide nanotube layers was prepared by electrochemical anodization of Ti foil in 0.4 wt% hydrofluoric acid solution. The nanotube layers structure and morphology were characterized using x-ray diffraction and scanning electron microscopy. The surface topography and wettability was studied according to the anodization time. The sample synthesized while the current density reached a local minimum displayed higher contact angle. Beyond this point, the contact angles decrease with the anodization time. Photo-degradation of acid orange 7 in aqueous solution was used as a probe to assess the photo-catalytic activity of titanium dioxide nanotube layers under UV irradiation. We obtained better photocatalitic activity for the sample elaborate at higher current density. Finally we use the Ciliated Protozoan T. pyriformis, an alternative cell model used for in vitro toxicity studies, to predict the toxicity of titanium dioxide nanotube layers in biological system. We did not observe any characteristic effect in the presence of the titanium dioxide nanotube layers on two physiological parameters related to this organism, non-specific esterases activity and population growth rate.
Here, we demonstrate two reliable routes for the fabrication of armchair-edge graphene nanoribbons (GNRs) on TbAu2/Au(111), belonging to a class of two-dimensional ferromagnetic rare earth-gold intermetallic compounds. On-surface synthesis directly on TbAu2 leads to the formation of GNRs, which are short and interconnected with each other. In contrast, the intercalation approach - on-surface synthesis of GNRs directly on Au(111) followed by rare earth intercalation - yields GNRs on TbAu2/Au(111), where both the ribbons and TbAu2 are of high quality comparable with those directly grown on clean Au(111). Besides, the as-grown ribbons retain the same band gap while changing from p-doping to weak n-doping mainly due to a change in the work function of the substrate after the rare earth intercalation. The intercalation approach might also be employed to fabricate other types of GNRs on various rare earth intermetallic compounds, providing platforms to tailor the electronic and magnetic properties of GNRs on magnetic substrates.