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Register a new userC$_{60}^+$ - looking for the bucky-ball in interstellar space
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Added by
Gazinur Galazutdinov
Publication date
2016
fields
Physics
and research's language is
English
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The laboratory gas phase spectrum recently published by Campbell et al. has reinvigorated attempts to confirm the presence of the C$_{60}^+$ cation in the interstellar medium, thorough an analysis of the spectra of hot, reddened stars. This search is hindered by at least two issues that need to be addressed: (i) the wavelength range of interest is severely polluted by strong water- vapour lines coming from the Earths atmosphere; (ii) one of the major bands attributed to C$_{60}^+$, at 9633 AA, is blended with the stellar Mg{sc ii} line, which is susceptible to non-local-thermodynamic equilibrium effects in hot stellar atmospheres. Both these issues are here carefully considered here for the first time, based on high-resolution and high signal-to-noise ratio echelle spectra for 19 lines of sight. The result is that the presence of C$_{60}^+$ in interstellar clouds is brought into question.
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We demonstrate, using the high resolution spectra from the ESPADONS spectrograph, fed with the 3.6m CFH telescope, that the strength ratios of the strong--to--weak spectral features, attributed to C$_{60}^+$, are variable. We found that in the range of expected 9366~AA C$_{60}^+$ feature there are two diffuse bands centered at 9362.0$pm$0.1 and 9365.3$pm$0.1 AA with variable intensity ratio. We confidently confirm the lack of 9428~AA feature which, in the laboratory spectra of C$_{60}^+$, is stronger than 9366~AA. The weakest laboratory feature, near 9348.4~AA, remains below the level of detection in all spectra. The intensity ratio 9577/9365 is variable. These facts contradict to their common origin and so -- the identification of some interstellar spectral features as being carried by the cation of the soccer ball. We also refined the rest wavelength position of the strongest diffuse band in this range: it is 9576.8$pm$0.1~AA.
Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 {AA} absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 {AA} and (strong) 9577 {AA} C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 {AA} band, and a conclusive confirmation of interstellar C60+.
In 2015, Campbell et al. (Nature 523, 322) presented spectroscopic laboratory gas phase data for the fullerene cation, C$_{60}^+$, that coincide with reported astronomical spectra of two diffuse interstellar band (DIB) features at 9633 and 9578 AA. In the following year additional laboratory spectra were linked to three other and weaker DIBs at 9428, 9366, and 9349 AA. The laboratory data were obtained using wavelength-dependent photodissociation spectroscopy of small (up to three) He-tagged C$_{60}^+-$He$_n$ ion complexes, yielding rest wavelengths for the bare C$_{60}^+$ cation by correcting for the He-induced wavelength shifts. Here we present an alternative approach to derive the rest wavelengths of the four most prominent C$_{60}^+$ absorption features, using high resolution laser dissociation spectroscopy of C$_{60}^+$ embedded in ultracold He droplets. Accurate wavelengths of the bare fullerene cation are derived based on linear wavelength shifts recorded for He$_n$C$_{60}^+$ species with $n$ up to 32. A careful analysis of all available data results in precise rest wavelengths (in air) for the four most prominent C$_{60}^+$ bands: 9631.9(1) AA, 9576.7(1) AA, 9427.5(1) AA, and 9364.9(1) AA. The corresponding band widths have been derived and the relative band intensity ratios are discussed.
The fullerene C$_{60}$ has four infrared-active vibrational transitions at 7.0, 8.5, 17.4 and 18.9 $mu$m. We have previously observed emission features at 17.4 and 18.9 $mu$m in the reflection nebula NGC 7023 and demonstrated spatial correlations suggestive of a common origin. We now confirm our earlier identification of these features with C$_{60}$ by detecting a third emission feature at 7.04 $pm$ 0.05 $mu$m in NGC 7023. We also report the detection of these three C$_{60}$ features in the reflection nebula NGC 2023. Our spectroscopic mapping of NGC 7023 shows that the 18.9 $mu$m C$_{60}$ feature peaks on the central star and that the 16.4 $mu$m emission feature due to polycyclic aromatic hydrocarbons peaks between the star and a nearby photodissociation front. The observed features in NGC 7023 are consistent with emission from UV-excited gas-phase C$_{60}$. We find that 0.1-0.6% of interstellar carbon is in C$_{60}$; this abundance is consistent with those from previous upper limits and possible fullerene detections in the interstellar medium. This is the first firm detection of neutral C$_{60}$ in the interstellar medium.
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide observational insights into these questions. C$_{60}$ is found to emit in PDRs where the dust is cool ($T_d = 20-40$ K) and even in PDRs with cool stars. These results exclude the possibility for C$_{60}$ to be locked in grains at thermal equilibrium in these environments. We observe that PAH and C$_{60}$ emission are spatially uncorrelated and that C$_{60}$ is present in PDRs where the physical conditions (in terms of radiation field and hydrogen density) allow for full dehydrogenation of PAHs, with the exception of Ced 201. We also find trends indicative of an increase in C$_{60}$ abundance within individual PDRs, but these trends are not universal. These results support models where the dehydrogenation of carbonaceous species is the first step towards C$_{60}$ formation. However, this is not the only parameter involved and C$_{60}$ formation is likely affected by shocks and PDR age.
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