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Disorder - impurities and defects violating an ideal order - is always present in solids. It can result in interesting and sometimes unexpected effects in multiband superconductors. Especially if the superconductivity is unconventional thus having other than the usual s-wave symmetry. This paper uses the examples of iron-based pnictides and chalcogenides to examine how both nonmagnetic and magnetic impurities affect superconducting states with $s_pm$ and $s_{++}$ order parameters. We show that disorder causes the transitions between $s_pm$ and $s_{++}$ states and examine observable effects these transitions can produce.
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We consider a problem of superconductivity coexistence with the spin-density-wave order in disordered multiband metals. It is assumed that random variations of the disorder potential on short length scales render the interactions between electrons to develop spatial correlations. As a consequence, both superconducting and magnetic order parameters become spatially inhomogeneous and are described by the universal phenomenological quantities, whereas all the microscopic details are encoded in the correlation function of the coupling strength fluctuations. We consider a minimal model with two nested two-dimensional Fermi surfaces and disorder potentials which include both intra- and inter-band scattering. The model is analyzed using the quasiclassical approach to show that short-scale pairing-potential disorder leads to a broadening of the coexistence region.
The theory of Andreev conductance is formulated for junctions involving normal metals (N) and multiband superconductors (S) and applied to the case of superconductors with nodeless extended $s_{pm}$-wave order parameter symmetry, as possibly realized in the recently discovered ferro pnictides. We find qualitative differences from tunneling into s-wave or d-wave superconductors that may help to identify such a state. First, interband interference leads to a suppression of Andreev reflection in the case of a highly transparent N/S interface and to a current deficit in the tunneling regime. Second, surface bound states may appear, both at zero and at non-zero energies. These effects do not occur in multiband superconductors without interband sign reversal, though the interference can still strongly modify the conductance spectra.
A single impurity problem is investigated for multiband s-wave superconductors with different sign order parameters (+-s-wave superconductors) suggested in Fe-pnictide superconductors. Not only intraband but also interband scattering is considered at the impurity. The latter gives rise to impurity-induced local boundstates close to the impurity. We present an exact form of the energy of the local boundstates as a function of strength of the two types of impurity scattering. The essential role of the impurity is unchanged in finite number of impurities. The main conclusions for a single impurity problem help us understand effects of dense impurities in the +-s-wave superconductors. Local density of states around the single impurity is also investigated. We suggest impurity site nuclear magnetic resonance as a suitable experiment to probe the local boundstates that is peculiar to the +-s-wave state. We find that the +-s-wave model is mapped to a chiral dx2-y2+-idxy-wave, reflecting the unconventional nature of the sign reversing order parameter. For a quantum magnetic impurity, interband scattering destabilizes the Kondo singlet.
Coexistence of antiferromagnetic order with superconductivity in many families of newly discovered iron-based superconductors has renewed interest to this old problem. Due to competition between the two types of order, one can expect appearance of the antiferromagnetism inside the cores of the vortices generated by the external magnetic field. The structure of a vortex in type II superconductors holds significant importance from the theoretical and the application points of view. Here we consider the internal vortex structure in a two-band s$_pm$ superconductor near a spin-density-wave instability. We treat the problem in a completely self-consistent manner within the quasiclassical Eilenberger formalism. We study the structure of the s$_pm$ superconducting order and magnetic field-induced spin-density-wave order near an isolated vortex. We examine the effect of this spin-density-wave state inside the vortex cores on the local density of states.
We implement the Bogoliubov-de Gennes (BdG) equation in real-space using the screened Korringa-Kohn-Rostoker (KKR) method. This allows us to solve, self-consistently, the superconducting state for 3d crystals including substitutional impurities with a full normal-state DFT band structure. We apply the theoretical framework to bulk Nb with impurities. Without impurities, Nb has an anisotropic gap structure with two distinct peaks around the Fermi level. In the presence of non-magnetic impurities those peaks are broadened due to the scattering between the two bulk superconducting gaps, however the peaks remain separated. As a second example of self-consistent real-space solutions of the BdG equations we examine superconducting clusters embedded within a non-superconducting bulk metallic host. This allows us to estimate the coherence length of the superconductor and we show that, within our framework, the coherence length of the superconductor is related to the inverse of the gap size, just as in bulk BCS theory.
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