The detection and study of molecular gas in born-again stars would be of great importance to understand their composition and chemical evolution. In addition, the molecular emission would be an invaluable tool to explore the physical conditions, kinematics and formation of asymmetric structures in the circumstellar envelopes of these evolved stars. However, until now, all attempts to detect molecular emission from the cool material around born-again stars have failed. We carried out observations using the APEX and IRAM 30m telescopes to search for molecular emission toward four well studied born-again stars, V4334 Sgr, V605 Aql, A30 and A78, that are thought to represent an evolutionary sequence. We detected for the first time emission from HCN and H$^{13}$CN molecules toward V4334 Sgr, and CO emission in V605 Aql. No molecular emission was detected above the noise level toward A30 and A78. A first estimate of the H$^{12}$CN/H$^{13}$CN abundance ratio in the circumstellar environment of V4334 Sgr is $approx$3, which is similar to the value of the $^{12}$C/$^{13}$C ratio measured from other observations. We derived a rotational temperature of $T_{rm rot}$=13$pm1$ K, and a total column density of $N_{{rm HCN}}$=1.6$pm0.1times$10$^{16}$ cm$^{-2}$ for V4334 Sgr. This result sets a lower limit on the amount of hydrogen that was ejected into the wind during the born-again event of this source. For V605 Aql, we obtained a lower limit for the integrated line intensities $I_{^{12}rm C}$/$I_{^{13}rm C}$>4.
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