We have performed an x-ray holotomography study of a three-dimensional (3D) photonic band gap crystal. The crystals was made from silicon by CMOS-compatible methods. We manage to obtain the 3D material density throughout the fabricated crystal. We observe that the structural design is for most aspects well-realized by the fabricated nanostructure. One peculiar feature is a slight shear-distortion of the cubic crystal structure. We conclude that 3D X-ray tomography has great potential to solve many future questions on optical metamaterials.
We present ultrafast optical switching experiments on 3D photonic band gap crystals. Switching the Si inverse opal is achieved by optically exciting free carriers by a two-photon process. We probe reflectivity in the frequency range of second order Bragg diffraction where the photonic band gap is predicted. We find good experimental switching conditions for free-carrier plasma frequencies between 0.3 and 0.7 times the optical frequency: we thus observe a large frequency shift of up to D omega/omega= 1.5% of all spectral features including the peak that corresponds to the photonic band gap. We deduce a corresponding large refractive index change of Dn_Si/n_Si= 2.0% and an induced absorption length that is longer than the sample thickness. We observe a fast decay time of 21 ps, which implies that switching could potentially be repeated at GHz rates. Such a high switching rate is relevant to future switching and modulation applications.
It is shown that total reflection for all incident angles does not require a two- or three-dimensional photonic crystal. We demonstrate that a one-dimensional photonic crystal can exhibit total omni-directional reflection for any incident wave within some frequency region. The formation of the omni-directional gap is discussed and a wide range of realistic fabrication parameters is proposed.
The paper shows that silicon-based 2D photonic crystal can be a promising material for acoustooptical devices. Isotropic and anisotropic Bragg diffraction of light in photonic crystal is considered. The computational method for calculation of frequency dependences of Bragg angle is developed. A simple method of optimization of photonic crystal parameters to obtain Bragg diffraction at necessary light and sound frequency is suggested.
Since thin-film silicon solar cells have limited optical absorption, we explore the effect of a nanostructured back reflector to recycle the unabsorbed light. As a back reflector we investigate a 3D photonic band gap crystal made from silicon that is readily integrated with the thin films. We numerically obtain the optical properties by solving the 3D time-harmonic Maxwell equations using the finite-element method, and model silicon with experimentally determined optical constants. The absorption enhancement relevant for photovoltaics is obtained by weighting the absorption spectra with the AM 1.5 standard solar spectrum. We study thin films either thicker ($L_{Si} = 2400$ nm) or much thinner ($L_{Si} = 80$ nm) than the wavelength of light. At $L_{Si} = 2400$ nm, the 3D photonic band gap crystal enhances the spectrally averaged ($lambda = 680$ nm to $880$ nm) silicon absorption by $2.22$x (s-pol.) to $2.45$x (p-pol.), which exceeds the enhancement of a perfect metal back reflector ($1.47$ to $1.56$x). The absorption is enhanced by the (i) broadband angle and polarization-independent reflectivity in the 3D photonic band gap, and (ii) the excitation of many guided modes in the film by the crystals surface diffraction leading to enhanced path lengths. At $L_{Si} = 80$ nm, the photonic crystal back reflector yields a striking average absorption enhancement of $9.15$x, much more than $0.83$x for a perfect metal, which is due to a remarkable guided mode confined within the combined thickness of the thin film and the photonic crystals Bragg attenuation length. The broad bandwidth of the 3D photonic band gap leads to the back reflectors Bragg attenuation length being much shorter than the silicon absorption length. Consequently, light is confined inside the thin film and the absorption enhancements are not due to the additional thickness of the photonic crystal back reflector.
Band gap modification for small-diameter (1 nm) silicon nanowires resulting from the use of different species for surface termination is investigated by density functional theory calculations. Because of quantum confinement, small-diameter wires exhibit a direct band gap that increases as the wire diameter narrows, irrespective of surface termination. This effect has been observed in previous experimental and theoretical studies for hydrogenated wires. For a fixed cross-section, the functional group used to saturate the silicon surface significantly modifies the band gap, resulting in relative energy shifts of up to an electronvolt. The band gap shifts are traced to details of the hybridization between the silicon valence band and the frontier orbitals of the terminating group, which is in competition with quantum confinement.