An unidentified infrared emission (UIE) feature at 6.0 $mu$m is detected in a number of astronomical sources showing the UIE bands. In contrast to the previous suggestion that this band is due to C=O vibrational modes, we suggest that the 6.0 $mu$m feature arises from olefinic double-bond functional groups. These groups are likely to be attached to aromatic rings which are responsible for the major UIE bands. The possibility that the formation of these functional groups is related to the hydrogenation process is discussed.
The [CII] 157.74 $mu$m transition is the dominant coolant of the neutral interstellar gas, and has great potential as a star formation rate (SFR) tracer. Using the Herschel KINGFISH sample of 46 nearby galaxies, we investigate the relation of [CII] surface brightness and luminosity with SFR. We conclude that [CII] can be used for measurements of SFR on both global and kiloparsec scales in normal star-forming galaxies in the absence of strong active galactic nuclei (AGN). The uncertainty of the $Sigma_{rm [CII]}-Sigma_{rm SFR}$ calibration is $pm$0.21 dex. The main source of scatter in the correlation is associated with regions that exhibit warm IR colors, and we provide an adjustment based on IR color that reduces the scatter. We show that the color-adjusted $Sigma_{rm[CII]}-Sigma_{rm SFR}$ correlation is valid over almost 5 orders of magnitude in $Sigma_{rm SFR}$, holding for both normal star-forming galaxies and non-AGN luminous infrared galaxies. Using [CII] luminosity instead of surface brightness to estimate SFR suffers from worse systematics, frequently underpredicting SFR in luminous infrared galaxies even after IR color adjustment (although this depends on the SFR measure employed). We suspect that surface brightness relations are better behaved than the luminosity relations because the former are more closely related to the local far-UV field strength, most likely the main parameter controlling the efficiency of the conversion of far-UV radiation into gas heating. A simple model based on Starburst99 population-synthesis code to connect SFR to [CII] finds that heating efficiencies are $1%-3%$ in normal galaxies.
Water ice has a strong spectral feature at a wavelength of approximately $3~mu$m, which plays a vital role in our understanding of the icy universe. In this study, we investigate the scattering polarization of this water-ice feature. The linear polarization degree of light scattered by $mu$m-sized icy grains is known to be enhanced at the ice band; however, the dependence of this polarization enhancement on various grain properties is unclear. We find that the enhanced polarization at the ice band is sensitive to the presence of $mu$m-sized grains as well as their ice abundance. We demonstrate that this enhancement is caused by the high absorbency of the water-ice feature, which attenuates internal scattering and renders the surface reflection dominant over internal scattering. Additionally, we compare our models with polarimetric observations of the low-mass protostar L1551 IRS 5. Our results show that scattering by a maximum grain radius of a few microns with a low water-ice abundance is consistent with observations. Thus, scattering polarization of the water-ice feature is a useful tool for characterizing ice properties in various astronomical environments.
The recent spectacular progress in the experimental and theoretical understanding of graphene, the basic constituent of graphite, is applied here to compute, from first principles, the UV extinction of nano-particles made of stacks of graphene layers. The theory also covers cases where graphene is affected by structural, chemical or orientation disorder, each disorder type being quantitatively defined by a single parameter. The extinction bumps carried by such model materials are found to have positions and widths falling in the same range as the known astronomical 2175 AA features: as the disorder parameter increases, the bump width increases from 0.85 to 2.5 $mu$m$^{-1}$, while its peak position shifts from 4.65 to 4.75 $mu$m$^{-1}$. Moderate degrees of disorder are enough to cover the range of widths of the vast majority of observed bumps (0.75 to 1.3 $mu$m$^{-1}$). Higher degrees account for outliers, also observed in the sky. The introduction of structural or chemical disorder amounts to changing the initial $sp^{2}$ bondings into $sp^{3}$ or $sp^{1}$, so the optical properties of the model material become similar to those of the more or less amorphous carbon-rich materials studied in the laboratory: a-C, a-C:H, HAC, ACH, coals etc. The present treatment thus bridges gaps between physically different model materials.
We report microscopic, cathodoluminescence, chemical and O isotopic measurements of FeO-poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2-ung), Northwest Africa 11086 (CM2-an), Allan Hills 77307 (CO3.0). The general petrographic, chemical and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand-alone objects. This indicates that they were splashed out of chondrules when these were still partially molten. CaO-rich refractory forsterites, which are restricted to $Delta^{17}O < -4permil$ likely escaped equilibration at lower temperatures because of their large size and possibly quicker quenching. The IOG thus bear witness to frequent collisions in the chondrule-forming regions.
We present the results of a study of the stellar activity in the solar neighborhood using complete kinematics (galactocentric velocities U,V,W) and the chromospheric activity index $log R_{rm{HK}}$. We analyzed the average activity level near the centers of known moving groups using a sample of 2529 stars and found that the stars near these associations tend to be more active than field stars. This supports the hypothesis that these structures, or at least a significant part of them, are composed of kinematically bound, young stars. We confirmed our results by using Galaxy Evolution Explorer (GALEX) UV data and kinematics taken from the Geneva-Copenhagen Survey for the stars in the sample. Finally, we present a compiled catalog with kinematics and activities for 2529 stars and a list of potential moving group members selected based on their stellar activity level.