According to the famous Kibble-Zurek mechanism (KZM), the universality of spontaneous defect generation in continuous phase transitions (CPTs) can be understood by the critical slowing down. In most CPTs of atomic Bose-Einstein condensates (BECs), the universality of spontaneous defect generations has been explained by the divergent relaxation time associated with the nontrivial gapless Bogoliubov excitations. However, for atomic BECs in synthetic gauge fields, their spontaneous superfluidity breakdown is resulted from the divergent correlation length associated with the zero Landau critical velocity. Here, by considering an atomic BEC ladder subjected to a synthetic magnetic field, we reveal that the spontaneous superfluidity breakdown obeys the KZM. The Kibble-Zurek scalings are derived from the Landau critical velocity which determines the correlation length. In further, the critical exponents are numerically extracted from the critical spatial-temporal dynamics of the bifurcation delay and the spontaneous vortex generation. Our study provides a general way to explore and understand the spontaneous superfluidity breakdown in CPTs from a single-well dispersion to a double-well one, such as, BECs in synthetic gauge fields, spin-orbit coupled BECs, and BECs in shaken optical lattices.