We construct discrete symmetry transformations for deformed relativistic kinematics based on group valued momenta. We focus on the specific example of kappa-deformations of the Poincare algebra with associated momenta living on (a sub-manifold of) de Sitter space. Our approach relies on the description of quantum states constructed from deformed kinematics and the observable charges associated with them. The results we present provide the first step towards the analysis of experimental bounds on the deformation parameter kappa to be derived via precision measurements of discrete symmetries and CPT.
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