We report on the crossover from the thermal to athermal regime of an artificial spin ice formed from a square array of magnetic islands whose lateral size, 30~nm~$times$~70~nm, is small enough that they are superparamagnetic at room temperature. We used resonant magnetic soft x-ray photon correlation spectroscopy (XPCS) as a method to observe the time-time correlations of the fluctuating magnetic configurations of spin ice during cooling, which are found to slow abruptly as a freezing temperature $T_0 = 178 pm 5$~K is approached. This slowing is well-described by a Vogel-Fulcher-Tammann law, implying that the frozen state is glassy, with the freezing temperature being commensurate with the strength of magnetostatic interaction energies in the array. The activation temperature, $T_mathrm{A} = 40 pm 10$~K, is much less than that expected from a Stoner-Wohlfarth coherent rotation model. Zero-field-cooled/field-cooled magnetometry reveals a freeing up of fluctuations of states within islands above this temperature, caused by variation in the local anisotropy axes at the oxidised edges. This Vogel-Fulcher-Tammann behavior implies that the system enters a glassy state on freezing, which is unexpected for a system with a well-defined ground state.
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