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Register a new userSynthesis, crystal structure, and magnetic properties of RE3Sb3Mg2O14 (RE=La, Pr, Sm, Eu, Tb, Ho): new 2D Kagome materials
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We present the crystal structures and magnetic properties of RE3Sb3Mg2O14 (La3Sb3Mg2O14, Pr3Sb3Mg2O14, Sm3Sb3Mg2O14, Eu3Sb3Mg2O14, Tb3Sb3Mg2O14, and Ho3Sb3Mg2O14), a family of novel materials based on a perfect geometry 2D rare earth Kagome lattice. Structure refinements were performed by the Rietveld method using X-ray diffraction data, indicating that the layered compounds are fully structurally ordered. The compounds crystallize in a rhombohedral supercell of the cubic pyrochlore structure, in the space group R-3m. As indicated by magnetic susceptibility measurements, they exhibit predominantly antiferromagnetic interactions between rare earth moments. Except for possibly Pr3Sb3Mg2O14 and Eu3Sb3Mg2O14, none of the compounds show any signs of magnetic ordering above 2 K. This RE3Sb3Mg2O14 family of compounds is similar to that of RE3Sb3Zn2O14, except the series reported here features a fully ordered distribution of cations in both the nonmagnetic antimony and magnesium sites and the magnetic rare earth kagome sites. The compounds appear to be relatively defect-free and are therefore model systems for investigating magnetic frustration on an ideal 2D rare earth Kagome lattice.
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We have investigated the temperature dependence of the magnetic susceptibility $chi(T)$ of rare-earth cobaltites RCoO$_3$ (R= La, Pr, Nd, Sm, Eu) in the temperature range $4.2-300$ K and also the influence of hydrostatic pressure up to 2 kbar on their susceptibility at fixed temperatures $T=78 $ and 300 K. The specific dependence $chi(T)$ observed in LaCoO$_3$ and the anomalously large pressure effect (d ln $chi$/d$Psim -100$ Mbar$^{-1}$ for $T = 78$ K) are analyzed in the framework of a two-level model with energy levels difference $Delta$. The ground state of the system is assumed to be nonmagnetic with the zero spin of Co$^{3+}$ ions, and magnetism at a finite temperature is determined by the excited magnetic spin state. The results of the analysis, supplemented by theoretical calculations of the electronic structure of LaCoO$_3$, indicate a significant increase in $Delta$ with a decrease in the unit cell volume under the hydrostatic pressure. In the series of RCoO$_3$ (R= Pr, Nd, Sm, Eu) compounds, the volume of crystal cell decreases monotonically due to a decrease in the radius of R$^{3+}$ ions. This leads to an increase in the relative energy $Delta$ of the excited state (the chemical pressure effect), which manifests itself in a decrease in the contribution of cobalt ions to the magnetic susceptibility at a fixed temperature, and also in a decrease in the hydrostatic pressure effect on the susceptibility of RCoO$_3$ compounds, which we have observed at $T=300$ K.
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