The liquid scintillator (LS) has been widely utilized in the past, running and future neutrino experiments, and requirement to the LS radio-purity is higher and higher. The water extraction is a powerful method to remove soluble radioactive nuclei, and a mini-extraction station has been constructed. To evaluate the extraction efficiency and optimize the operation parameters, a setup to load radioactivity to LS and a laboratory scale setup to measure radioactivity which use Bi^{212}-Po^{212}-Pb^{208} cascade decay are developed. Experiences from laboratory study will be useful to large scale water extraction plants design and the optimization of working in future.