We present temporal intensity correlation measurements of light scattered by a hot atomic vapor. Clear evidence of photon bunching is shown at very short time-scales (nanoseconds) imposed by the Doppler broadening of the hot vapor. Moreover, we demonstrate that relevant information about the scattering process, such as the ratio of single to multiple scattering, can be deduced from the measured intensity correlation function. These measurements confirm the interest of temporal intensity correlation to access non-trivial spectral features, with potential applications in astrophysics.