The Galactic Ridge X-ray Emission (GRXE) spectrum has strong iron emission lines at 6.4, 6.7, and 7.0~keV, each corresponding to the neutral (or low-ionized), He-like, and H-like iron ions. The 6.4~keV fluorescence line is due to irradiation of neutral (or low ionized) material (iron) by hard X-ray sources, indicating uniform presence of the cold matter in the Galactic plane. In order to resolve origin of the cold fluorescent matter, we examined the contribution of the 6.4~keV line emission from white dwarf surfaces in the hard X-ray emitting symbiotic stars (hSSs) and magnetic cataclysmic variables (mCVs) to the GRXE. In our spectral analysis of 4~hSSs and 19~mCVs observed with Suzaku, we were able to resolve the three iron emission lines. We found that the equivalent-widths (EWs) of the 6.4~keV lines of hSSs are systematically higher than those of mCVs, such that the average EWs of hSSs and mCVs are $179_{-11}^{+46}$~eV and $93_{-3}^{+20}$~eV, respectively. The EW of hSSs compares favorably with the typical EWs of the 6.4~keV line in the GRXE of 90--300~eV depending on Galactic positions. Average 6.4~keV line luminosities of the hSSs and mCVs are $9.2times 10^{39}$ and $1.6times 10^{39}$~photons~s$^{-1}$, respectively, indicating that hSSs are intrinsically more efficient 6.4~keV line emitters than mCVs. We compare expected contribution of the 6.4 keV lines from mCVs with the observed GRXE 6.4 keV line flux in the direction of $(l,b) approx (28.5arcdeg, 0arcdeg$). We conclude that almost all the 6.4 keV line flux in GRXE may be explained by mCVs within current undertainties of the stellar number densities, while contribution from hSSs may not be negligible.
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