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Register a new userNarrow Zero-Field Tunneling Resonance in Triclinic Mn$_{12}$ Acetate Ribbons
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We report synthesis, structural characterization, and magnetic measurements of amorphous Mn$_{12}$-acetate ribbons with a triclinic short-range crystal order not previously seen in experiment. The ribbons exhibit the same structure of Mn$_{12}$ molecules and the same positions of tunneling resonances on the magnetic field as a conventional tetragonal Mn$_{12}$-acetate crystal. However, the width of the zero-field resonance is by at least one order of magnitude smaller, indicating very small inhomoge- neous broadening due to dipolar and nuclear fields. Possible origins of this effect are discussed.
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We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn$_{12}$ acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for Mn$_{12}$ acetate. Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for a single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn$_{12}$ acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.
We report measurements of the magnetic susceptibility of single crystals of Mn$_{12}$-acetate-MeOH, a new high-symmetry variant of the original single molecule magnet Mn$_{12}$-acetate. A comparison of these data to theory and to data for the Mn$_{12}$ acetate material shows that Mn$_{12}$-acetate-MeOH is a realization of a transverse-field Ising ferromagnet in contrast to the original Mn$_{12}$ acetate material, in which solvent disorder leads to effects attributed to random field Ising ferromagnetism.
In magnetic fields applied parallel to the anisotropy axis, the magnetization of Mn$_{12}$ has been measured in response to a field that is swept back and forth across the resonances corresponding to steps $N=4,5,...9$. The fraction of molecules remaining in the metastable well after each sweep through the resonance is inconsistent with expectations for an ensemble of identical molecules. The data are consistent instead with the presence of a broad distribution of tunnel splittings. A very good fit is obtained for a Gaussian distribution of the second-order anisotropy tunneling parameter $X_E=-ln(mid Emid/2D)$. We show that dipolar shuffling is a negligible effect which cannot explain our data.
A ribbon is a surface swept out by a line segment turning as it moves along a central curve. For narrow magnetic ribbons, for which the length of the line segment is much less than the length of the curve, the anisotropy induced by the magnetostatic interaction is biaxial, with hard axis normal to the ribbon and easy axis along the central curve. The micromagnetic energy of a narrow ribbon reduces to that of a one-dimensional ferromagnetic wire, but with curvature, torsion and local anisotropy modified by the rate of turning. These general results are applied to two examples, namely a helicoid ribbon, for which the central curve is a straight line, and a Mobius ribbon, for which the central curve is a circle about which the line segment executes a $180^circ$ twist. In both examples, for large positive tangential anisotropy, the ground state magnetization lies tangent to the central curve. As the tangential anisotropy is decreased, the ground state magnetization undergoes a transition, acquiring an in-surface component perpendicular to the central curve. For the helicoid ribbon, the transition occurs at vanishing anisotropy, below which the ground state is uniformly perpendicular to the central curve. The transition for the Mobius ribbon is more subtle; it occurs at a positive critical value of the anisotropy, below which the ground state is nonuniform. For the helicoid ribbon, the dispersion law for spin wave excitations about the tangential state is found to exhibit an asymmetry determined by the geometric and magnetic chiralities.
Local time-resolved measurements of fast reversal of the magnetization of single crystals of Mn12-acetate indicate that the magnetization avalanche spreads as a narrow interface that propagates through the crystal at a constant velocity that is roughly two orders of magnitude smaller than the speed of sound. We argue that this phenomenon is closely analogous to the propagation of a flame front (deflagration) through a flammable chemical substance.
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