We present Submillimeter Array (SMA) molecular line observations in two 2 GHz-wide bands centered at 217.5 and 227.5 GHz, toward the massive star forming region W51 North. We identified 84 molecular line transitions from 17 species and their isotopologues. The molecular gas distribution of these lines mainly peaks in the continuum position of W51 North, and has a small tail extending to the west, probably associated with W51 d2. In addition to the commonly detected nitrogen and oxygen-bearing species, we detected a large amount of transitions of the Acetone (CH$_3$COCH$_3$) and Methyl Formate (CH$_3$OCHO), which may suggest that these molecules are present in an early evolutionary stage of the massive stars. We also found that W51 North is an ethanol-rich source. There is no obvious difference in the molecular gas distributions between the oxygen-bearing and nitrogen-bearing molecules. Under the assumption of Local Thermodynamic Equilibrium (LTE), with the XCLASS tool, the molecular column densities, and rotation temperatures are estimated. We found that the oxygen-bearing molecules have considerable higher column densities and fractional abundances than the nitrogen-bearing molecules. The rotation temperatures range from 100 to 200 K, suggesting that the molecular emission could be originated from a warm environment. Finally, based on the gas distributions, fractional abundances and the rotation temperatures, we conclude that CH$_3$OH, C$_2$H$_5$OH, CH$_3$COCH$_3$ and CH$_3$CH$_2$CN might be synthesized on the grain surface, while gas phase chemistry is responsible for the production of CH$_3$OCH$_3$, CH$_3$OCHO and CH$_2$CHCN.
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