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Register a new userIdentifying Student Difficulties with Entropy, Heat Engines, and the Carnot Cycle
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We report on several specific student difficulties regarding the Second Law of Thermodynamics in the context of heat engines within upper-division undergraduates thermal physics courses. Data come from ungraded written surveys, graded homework assignments, and videotaped classroom observations of tutorial activities. Written data show that students in these courses do not clearly articulate the connection between the Carnot cycle and the Second Law after lecture instruction. This result is consistent both within and across student populations. Observation data provide evidence for myriad difficulties related to entropy and heat engines, including students struggles in reasoning about situations that are physically impossible and failures to differentiate between differential and net changes of state properties of a system. Results herein may be seen as the application of previously documented difficulties in the context of heat engines, but others are novel and emphasize the subtle and complex nature of cyclic processes and heat engines, which are central to the teaching and learning of thermodynamics and its applications. Moreover, the sophistication of these difficulties is indicative of the more advanced thinking required of students at the upper division, whose developing knowledge and understanding give rise to questions and struggles that are inaccessible to novices.
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We describe a study on the conceptual difficulties faced by college students in understanding hydrodynamics of ideal fluids. This study was based on responses obtained in hundreds of written exams and oral interviews, which were held with first-year Engineering and Science university students. Their responses allowed us to identify a series of misconceptions unreported in the literature so far. The study findings demonstrate that the most important difficulties arise from the students inability to establish a link between the kinematics and dynamics of moving fluids, and from a lack of understanding regarding how different regions of a system interact.
We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result, there is a working-substance-dependent correction to the usual Carnot efficiency, which is valid only when the working substance is in the thermodynamic limit. We derives a general and simple expression for the maximum efficiency of a Carnot cycle heat engine in terms of the relative entropy. This maximum efficiency approaches the usual Carnot efficiency asymptotically when the size of the working substance increases to the thermodynamic limit. Our study extends the Carnots result to cases with arbitrary size working substance and demonstrates the subtlety of thermodynamics in small systems.
Entropy is one of the most basic concepts in thermodynamics and statistical mechanics. The most widely used definition of statistical mechanical entropy for a quantum system is introduced by von Neumann. While in classical systems, the statistical mechanical entropy is defined by Gibbs. The relation between these two definitions of entropy is still not fully explored. In this work, we study this problem by employing the phase-space formulation of quantum mechanics. For those quantum states having well-defined classical counterparts, we study the quantum-classical correspondence and quantum corrections of the entropy. We expand the von Neumann entropy in powers of ${hbar}$ by using the phase-space formulation, and the zeroth order term reproduces the Gibbs entropy. We also obtain the explicit expression of the quantum corrections of the entropy. Moreover, we find that for the thermodynamic equilibrium state, all terms odd in ${hbar}$ are exactly zero. As an application, we derive quantum corrections for the net work extraction during a quantum Carnot cycle. Our results bring important insights to the understanding of quantum entropy and may have potential applications in the study of quantum heat engines.
Knowledge of quantum mechanical systems is becoming more important for many science and engineering students who are looking to join the emerging quantum workforce. To better prepare a wide range of students for these careers, we must seek to develop new tools to enhance our education in quantum topics. We present initial studies on the use of one of these such tools, Quantum Composer, a 1D quantum simulation and visualization tool developed for education and research purposes. In particular, we conducted five think-aloud interviews with students who worked through an exercise using Quantum Composer that focused on the statics and dynamics of quantum states in single- and double-harmonic well systems. Our results show that Quantum Composer helps students to obtain the correct answers to the questions posed, but additional support is needed to facilitate the development of student reasoning behind these answers. In addition, we find that students explore familiar and unfamiliar problems in similar ways, indicating that Quantum Composer is a useful tool for exploring systems that students have not seen before.
Recently, Zhang {em et al.} [PRA, {bf 75}, 062102 (2007)] extended Kieus interesting work on the quantum Otto engine [PRL, {bf 93}, 140403 (2004)] by considering as working substance a bipartite quantum system $AB$ composed of subsystems $A$ and $B$. In this paper, we express the net work done $W_{AB}$ by such an engine explicitly in terms of the macroscopic bath temperatures and information theoretic quantities associated with the microscopic quantum states of the working substance. This allows us to gain insights into the dependence of positive $W_{AB}$ on the quantum properties of the states. We illustrate with a two-qubit XY chain as the working substance. Inspired by the expression, we propose a plausible formula for the work derivable from the subsystems. We show that there is a critical entanglement beyond which it is impossible to draw positive work locally from the individual subsystems while $W_{AB}$ is positive. This could be another interesting manifestation of quantum nonlocality.
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