Light beams having a vectorial field structure - or polarization - that varies over the transverse profile and a central optical singularity are called vector-vortex (VV) beams and may exhibit specific properties, such as focusing into light needles or rotation invariance, with applications ranging from microscopy and light trapping to communication and metrology. Individual photons in such beams exhibit a form of single-particle quantum entanglement between different degrees of freedom. On the other hand, the quantum states of two photons can be also entangled with each other. Here we combine these two concepts and demonstrate the generation of quantum entanglement between two photons that are both in VV states - a new form of quantum entangled entanglement. This result may lead to quantum-enhanced applications of VV beams as well as to quantum-information protocols fully exploiting the vectorial features of light.
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