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Register a new userPlanetary and meteoritic Mg/Si and d30Si variations inherited from solar nebula chemistry
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The bulk chemical compositions of planets are uncertain, even for major elements such as Mg and Si. This is due to the fact that the samples available for study all originate from relatively shallow depths. Comparison of the stable isotope compositions of planets and meteorites can help overcome this limitation. Specifically, the non-chondritic Si isotope composition of the Earths mantle was interpreted to reflect the presence of Si in the core, which can also explain its low density relative to pure Fe-Ni alloy. However, we have found that angrite meteorites display a heavy Si isotope composition similar to the lunar and terrestrial mantles. Because core formation in the angrite parent-body (APB) occurred under oxidizing conditions at relatively low pressure and temperature, significant incorporation of Si in the core is ruled out as an explanation for this heavy Si isotope signature. Instead, we show that equilibrium isotopic fractionation between gaseous SiO and solid forsterite at 1370 K in the solar nebula could have produced the observed Si isotope variations. Nebular fractionation of forsterite should be accompanied by correlated variations between the Si isotopic composition and Mg/Si ratio following a slope of 1, which is observed in meteorites. Consideration of this nebular process leads to a revised Si concentration in the Earths core of 3.6 (+6.0/-3.6) wt% and provides estimates of Mg/Si ratios of bulk planetary bodies.
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Chondrules formed by the melting of dust aggregates in the solar protoplanetary disk and as such provide unique insights into how solid material was transported and mixed within the disk. Here we show that chondrules from enstatite and ordinary chondrites show only small 50Ti variations and scatter closely around the 50Ti composition of their host chondrites. By contrast, chondrules from carbonaceous chondrites have highly variable 50Ti compositions, which, relative to the terrestrial standard, range from the small 50Ti deficits measured for enstatite and ordinary chondrite chondrules to the large 50Ti excesses known from Ca-Al-rich inclusions (CAIs). These 50Ti variations can be attributed to the addition of isotopically heterogeneous CAI-like material to enstatite and ordinary chondrite-like chondrule precursors. The new Ti isotopic data demonstrate that isotopic variations among carbonaceous chondrite chondrules do not require formation over a wide range of orbital distances, but can instead be fully accounted for by the incorporation of isotopically anomalous nuggets into chondrule precursors. As such, these data obviate the need for disk-wide transport of chondrules prior to chondrite parent body accretion and are consistent with formation of chondrules from a given chondrite group in localized regions of the disk. Lastly, the ubiquitous presence of 50Ti-enriched material in carbonaceous chondrites, and the lack of this material in the non-carbonaceous chondrites support the idea that these two meteorite groups derive from areas of the disk that remained isolated from each other through the formation of Jupiter.
Isotope anomalies provide important information about early solar system evolution. Here we report molybdenum isotope abundances determined in samples of various meteorite classes. There is no fractionation of molybdenum isotopes in our sample set within 0.1 permil and no contribution from the extinct radionuclide 97Tc at mass 97 (97Tc/92Mo<3E-6). Instead, we observe clear anomalies in bulk iron meteorites, mesosiderites, pallasites, and chondrites characterized by a coupled excess in p- and r- or a mirror deficit in s-process nuclides (Mo-HL). This large scale isotope heterogeneity of the solar system observed for molybdenum must have been inherited from the interstellar environment where the sun was born, illustrating the concept of ``cosmic chemical memory. The presence of molybdenum anomalies is used to discuss the filiation between planetesimals.
We review recent advances in our understanding of magnetism in the solar nebular and protoplanetary disks (PPDs). We discuss the implications of theory, meteorite measurements, and astronomical observations for planetary formation and nebular evolution. Paleomagnetic measurements indicate the presence of fields of 0.54$pm$0.21 G at $sim$1 to 3 astronomical units (AU) from the Sun and $gtrsim$0.06 G at 3 to 7 AU until >1.22 and >2.51 million years (Ma) after solar system formation, respectively. These intensities are consistent with those predicted to enable typical astronomically-observed protostellar accretion rates of $sim$10$^{-8}$ M$_odot$ yr$^{-1}$, suggesting that magnetism played a central role in mass and angular momentum transport in PPDs. Paleomagnetic studies also indicate fields <0.006 G and <0.003 G in the inner and outer solar system by 3.94 and 4.89 Ma, respectively, consistent with the nebular gas having dispersed by this time. This is similar to the observed lifetimes of extrasolar protoplanetary disks.
Several of NASA missions (TESS, JWST, WFIRST, etc.) and mission concepts (LUVOIR, HabEx, and OST) emphasize the exploration and characterization of exoplanets, and the study of the interstellar medium. We anticipate that a much broader set of chemical environments exists on exoplanets, necessitating data from a correspondingly broader set of chemical reactions. Similarly, the conditions that exist in astrophysical environments are very different from those traditionally probed in laboratory chemical kinetics studies. These are areas where quantum mechanical theory, applied to important reactions via well-validated chemical kinetics models, can fill a critical knowledge gap. Quantum chemical calculations are also introduced to study interior of planets, photochemical escape, and many critical chemical pathways (e.g. prebiotic environments, contaminations, etc.) After years of development of the relevant quantum chemical theories and significant advances in computational power, quantum chemical simulations have currently matured enough to describe real systems with an accuracy that competes with experiments. These approaches, therefore, have become the best possible alternative in many circumstances where performing experiments is too difficult, too expensive, or too dangerous, or simply not possible. In this white paper, several existing quantum chemical studies supporting exoplanetary science, planetary astronomy, and astrophysics are described, and the potential positive impacts of improved models associated with scientific goals of missions are addressed. In the end, a few recommendations from the scientific community to strengthen related research efforts at NASA are provided.
Solar photospheric abundances of refractory elements mirror the Earths to within ~10 mol% when normalized to the dominant terrestrial planet-forming elements Mg, Si and Fe. This allows for the adoption of Solar composition as an order-of-magnitude proxy for Earths. It is not known, however, the degree to which this mirroring of stellar and terrestrial planet abundances holds true for other star-planet systems without determination of the composition of initial planetesimals via condensation sequence calculations and post condensation processes. We present the open-source Arbitrary Composition Condensation Sequence calculator (ArCCoS) to assess how the elemental composition of a parent star affects that of the planet-building material, including the extent of oxidation within the planetesimals. We demonstrate the utility of ArCCoS by showing how variations in the abundance of the stellar refractory elements Mg and Si affect the condensation of oxygen, a controlling factor in the relative proportions of planetary core and silicate mantle material. This, thereby, removes significant degeneracy in the interpretation of the structures of exoplanets as well as providing observational tests for the validity of this model.
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