Multiple Partonic Interactions are often crucial for interpreting results obtained at the Large Hadron Collider (LHC). The quest for a sound understanding of the dynamics behind MPI - particularly at this time when the LHC is due to start its Run II operations - has focused the aim of this workshop. MPI@LHC2014 concentrated mainly on the phenomenology of LHC measurements whilst keeping in perspective those results obtained at previous hadron colliders. The workshop has also debated some of the state-of-the-art theoretical considerations and the modeling of MPI in Monte Carlo event generators. The topics debated in the workshop included: Phenomenology of MPI processes and multiparton distributions; Considerations for the description of MPI in Quantum Chromodynamics (QCD); Measuring multiple partonic interactions; Experimental results on inelastic hadronic collisions: underlying event, minimum bias, forward energy flow; Monte Carlo generator development and tuning; Connections with low-x phenomena, diffraction, heavy-ion physics and cosmic rays. In a total of 57 plenary talks the workshop covered a wide range of experimental results, Monte Carlo development and tuning, phenomenology and dedicated measurements of MPI which were produced with data from the LHCs Run I. Recent progress of theoretical understanding of MPI in pp, pA and AA collisions as well as the role of MPI in diffraction and small-x physics were also covered. The workshop forstered close contact between the experimental and theoretical communities. It provided a setting to discuss many of the different aspects of MPI, eventually identifying them as a unifying concept between apparently different lines of research and evaluating their impact on the LHC physics programme.