Do you want to publish a course? Click here

Order-disorder type critical behaviour at the magnetoelectric phase transition in multiferroic DyMnO$_3$

125   0   0.0 ( 0 )
 Added by Markus Schiebl
 Publication date 2015
  fields Physics
and research's language is English




Ask ChatGPT about the research

We present the results of detailed dielectric investigations of the relaxation dynamics in DyMnO$_3$ multiferroic manganite. Strong low-frequency relaxation process near the paraelectric-ferroelectric phase transition is observed. The high frequency mode is directly to the relaxational motion of multiferroic domain walls. We provide an experimental evidence that this relaxation mode corresponds to a chirality switching of the spin cycloid in DyMnO$_3$. We demonstrate that the relaxation dynamics in DyMnO$_3$ is typical for an order-disorder phase transition and may be understood within a simple model with a double well potential. DyMnO$_3$ follows an order-disorder transition scenario implicating that a short range cycloidal order of Mn-spins exists above $T_C$. These results suggest the interpretation of the paraelectric sinusoidal phase in manganites as a dynamical equilibrium of magnetic cycloids with opposite chiralities.



rate research

Read More

125 - Bin Xu , Olle Hellman , 2019
The prototypical antiferroelectric PbZrO$_3$ has several unsettled questions, such as the nature of the antiferroelectric transition, possible intermediate phase and the microscopic origin of the Pbam ground state. Using first principles, we show that no phonon becomes truly soft at the cubic-to-Pbam transition temperature, and the order-disorder character of this transition is clearly demonstrated based on molecular dynamics simulations and potential energy surfaces. The out-of-phase octahedral tilting is an important degree of freedom, which can collaborate with other phonon distortions and form a complex energy landscape with multiple minima. Candidates of the possible intermediate phase are suggested based on the calculated kinetic barriers between energy minima, and the development of a first-principles-based effective Hamiltonian. The use of this latter scheme further reveals that specific bi-linear interactions between local dipoles and octahedral tiltings play a major role in the formation of the Pbam ground state, which contrasts with most of the previous explanations.
Electric and magnetic properties of multiferroic GdMn2O5 in external magnetic fields were investigated to map out the magnetoelectric phases in this material. Due to strong magnetoelectric coupling, the dielectric permittivity is highly sensitive to phase boundaries in GdMn2O5, which allowed to construct the field-temperature phase diagrams. Several phase transitions are observed which are strongly field-dependent with respect to field orientation and strength. The phase diagram for a magnetic field along the crystallographic a-axis corresponds well to a polarization step, as induced by 90 degree rotation of Gd magnetic moments. Our results support the model of two ferroelectric sublattices, Mn-Mn and Gd-Mn with strong R-Mn (4f-3d) interaction for the polarization in RMn2O5.
Using first-principles calculations we predict that the layered-perovskite metal Bi$_5$Mn$_5$O$_{17}$ is a ferromagnet, ferroelectric, and ferrotoroid which may realize the long sought-after goal of a room-temperature ferromagnetic single-phase multiferroic with large, strongly coupled, primary-order polarization and magnetization. Bi$_5$Mn$_5$O$_{17}$ has two nearly energy-degenerate ground states with mutually orthogonal vector order parameters (polarization, magnetization, ferrotoroidicity), which can be rotated globally by switching between ground states. Giant cross-coupling magnetoelectric and magnetotoroidic effects, as well as optical non-reciprocity, are thus expected. Importantly, Bi$_5$Mn$_5$O$_{17}$ should be thermodynamically stable in O-rich growth conditions, and hence experimentally accessible.
In this article the mechanism of the linear magnetoelectric (ME) effect in the rhombohedral multiferroic BiFeO$_3$ is considered. The study is based on the symmetry approach of the GinzburgLandau type, in which polarization, antiferrodistortion, and antiferromagnetic momentum vectors are viewed as ordering parameters. We demonstrate that the linear ME effect in BFO is caused by reorientation of the antiferrodistortion vector in either electric or magnetic field. The numerical estimations, which show quantitative agreement with the results of the recent measurements in film samples, have been performed. A possibility of significant enhancement of the magnetoelectric effect by applying an external static electric field has been investigated. The considered approach is promising for explaining the high values of the ME effect in composite films and heterostructures with BFO.
Clear anomalies in the lattice thermal expansion (deviation from linear variation) and elastic properties (softening of the sound velocity) at the antiferromagnetic-to-paramagnetic transition are observed in the prototypical multiferroic BiFeO3 using a combination of picosecond acoustic pump-probe and high-temperature X-ray diffraction experiments. Similar anomalies are also evidenced using first-principles calculations supporting our experimental findings. Those calculations in addition to a simple Landau-like model we also developed allow to understand the elastic softening and lattice change at T_N as a result of magnetostriction combined with electrostrictive and magnetoelectric couplings which renormalize the elastic constants of the high-temperature reference phase when the critical T_N temperature is reached.
comments
Fetching comments Fetching comments
Sign in to be able to follow your search criteria
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا