We study the distribution, masses, and dynamical properties of galaxy groups in the A2142 supercluster. We analyse the global luminosity density distribution in the supercluster and divide the supercluster into the high-density core and the low-density outskirts regions. We find galaxy groups and filaments in the regions of different global density, calculate their masses and mass-to-light ratios and analyse their dynamical state with several 1D and 3D statistics. We use the spherical collapse model to study the dynamical state of the supercluster. We show that in A2142 supercluster groups and clusters with at least ten member galaxies lie along an almost straight line forming a 50 Mpc/h long main body of the supercluster. The A2142 supercluster has a very high density core surrounded by lower-density outskirt regions. The total estimated mass of the supercluster is M_est = 6.2 10^{15}M_sun. More than a half of groups with at least ten member galaxies in the supercluster lie in the high-density core of the supercluster, centered at the rich X-ray cluster A2142. Most of the galaxy groups in the core region are multimodal. In the outskirts of the supercluster, the number of groups is larger than in the core, and groups are poorer. The orientation of the cluster A2142 axis follows the orientations of its X-ray substructures and radio halo, and is aligned along the supercluster axis. The high-density core of the supercluster with the global density D8 > 17 and perhaps with D8 > 13 may have reached the turnaround radius and started to collapse. A2142 supercluster with luminous, collapsing core and straight body is an unusual object among galaxy superclusters. In the course of the future evolution the supercluster may be split into several separate systems.